Answer
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Hint: Acetic acid is a carboxylic acid containing \[ - COOH\] a group. It donates protons and shows acidity. It is also called protonic acid. Benzene is a cyclic compound, containing carbon. Benzene is liquid at room temperature, so it can be used as a solvent in many reactions. It can dissolve any organic molecules.
Complete step by step answer:
In the case of acetic acid, due to the presence of \[C - O\] bonds, it is a polar molecule. Due to this polar nature, it can also dissolve into a polar solvent like water. In polar solvents, acetic acid can dissociate and generate protons. Now, benzene is an anion polar molecule. So, dissociation of acetic acid in benzene is not possible.
Therefore, acetic acid molecules form hydrogen bonding in benzene solvent. In this case, the two acetic acid molecules form intermolecular hydrogen bonding and form a dimer. The structure of the dimer is shown below,
Hence option B is correct.
Additional information:
The acidity of an organic compound is depending upon the electron deficiency of the hydrogen atom. The higher the electron deficiency of the hydrogen higher will be the acidity character of that hydrogen.
Now to be acidic hydrogen that hydrogen should be attached with a high electronegative group or electron-withdrawing group. The higher the electronegativity of the group, the higher will be the electron deficiency of the hydrogen, attached to that group as well as the acidity.
In the case of acetic acid, the hydrogen is attached with the high electronegative oxygen atom, as a result, an electron deficiency is formed on hydrogen, and shows acidity.
The acidity of the carboxylic acid depends upon the electronic nature of the group attached to a carboxylic acid. The higher the electron-withdrawing nature of the group higher will be the acidity and vice-versa.
Note:
Now to be acidic hydrogen that hydrogen should be attached with a high electronegative group or electron-withdrawing group. The higher the electronegativity of the group, the higher will be the electron deficiency of the hydrogen, attached to that group as well as the acidity. Now in the case or carbon, the electronegativity varies with hybridization. With increasing the s character in the hybridization electronegativity of the carbon increases and vice-versa. Now the order of the electronegativity of the different hybridization of carbon Is \[s{p^3} < s{p^2} < sp\] . Therefore, the order of the acidity of the hydrogen attached to these hybridized carbons is \[{C_{s{p^3}}} - H < {C_{s{p^2}}} - H < {C_{sp}} - H\] .
Complete step by step answer:
In the case of acetic acid, due to the presence of \[C - O\] bonds, it is a polar molecule. Due to this polar nature, it can also dissolve into a polar solvent like water. In polar solvents, acetic acid can dissociate and generate protons. Now, benzene is an anion polar molecule. So, dissociation of acetic acid in benzene is not possible.
Therefore, acetic acid molecules form hydrogen bonding in benzene solvent. In this case, the two acetic acid molecules form intermolecular hydrogen bonding and form a dimer. The structure of the dimer is shown below,
Hence option B is correct.
Additional information:
The acidity of an organic compound is depending upon the electron deficiency of the hydrogen atom. The higher the electron deficiency of the hydrogen higher will be the acidity character of that hydrogen.
Now to be acidic hydrogen that hydrogen should be attached with a high electronegative group or electron-withdrawing group. The higher the electronegativity of the group, the higher will be the electron deficiency of the hydrogen, attached to that group as well as the acidity.
In the case of acetic acid, the hydrogen is attached with the high electronegative oxygen atom, as a result, an electron deficiency is formed on hydrogen, and shows acidity.
The acidity of the carboxylic acid depends upon the electronic nature of the group attached to a carboxylic acid. The higher the electron-withdrawing nature of the group higher will be the acidity and vice-versa.
Note:
Now to be acidic hydrogen that hydrogen should be attached with a high electronegative group or electron-withdrawing group. The higher the electronegativity of the group, the higher will be the electron deficiency of the hydrogen, attached to that group as well as the acidity. Now in the case or carbon, the electronegativity varies with hybridization. With increasing the s character in the hybridization electronegativity of the carbon increases and vice-versa. Now the order of the electronegativity of the different hybridization of carbon Is \[s{p^3} < s{p^2} < sp\] . Therefore, the order of the acidity of the hydrogen attached to these hybridized carbons is \[{C_{s{p^3}}} - H < {C_{s{p^2}}} - H < {C_{sp}} - H\] .
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