Question

An example of pyrosilicate is:
A) Thortveitite
B) Willemite
C) Spodumene
D) Kaolinite

Answer 1

Hint: The silicate is formed by fusing an alkali with the$\text{ Si}{{\text{O}}_{\text{2}}}$. It exists in various allotropes like Orthosilicate, pyrosilicate, cyclic silicate, chain silicate, etc. The pyrosilicate consists of the $\text{ S}{{\text{i}}_{\text{2}}}\text{O}_{\text{7}}^{\text{6-}}$ anions which are joined together by the removal of oxygen. The thortveitite is an example of silicate, it is scandium yttrium silicate. $\text{ (Sc,Y}{{\text{)}}_{\text{2}}}\text{S}{{\text{i}}_{\text{2}}}{{\text{O}}_{\text{7}}}$


Complete step by step answer:
The $\text{ Si}{{\text{O}}_{\text{2}}}$ fuses with the alkali oxides to give silicates. This is discrete tetrahedral units. Since silicon is \[\text{ s}{{\text{p}}^{\text{3}}}\] hybridized. The various units are linked in several patterns and classified as follows,
1) Orthosilicate: Orthosilicate contains the separated $\text{ Si}{{\text{O}}_{4}}$units. This is linked together by various patterns. An example is Willemite$\text{ (ZrSi}{{\text{O}}_{\text{4}}}\text{)}$.
2) Pyrosilicate: In pyrosilicate, the two units are linked together by the oxygen atom. The simplest ion is\[\text{ S}{{\text{i}}_{\text{2}}}{{\text{O}}_{\text{7}}}\] . Example is Thortveitite\[\text{ S}{{\text{c}}_{\text{2}}}\left[ \text{S}{{\text{i}}_{\text{2}}}{{\text{O}}_{\text{7}}} \right]\]
3) Cyclic silicates: this allotrope shares the two oxygen atoms. The example is Beryl - \[\text{ B}{{\text{e}}_{\text{3}}}\text{A}{{\text{l}}_{\text{2}}}\text{S}{{\text{i}}_{\text{6}}}{{\text{O}}_{\text{18}}}\]
4) Chain silicates: these are formed by the linking of units to form a chain silicate. They are of two types:
i) Metasilicates
ii) Amphiboles
Now, we will discuss pyrosilicate. A pyrosilicate is a chemical compound that contains the phyllosilicate anion $\text{ S}{{\text{i}}_{\text{2}}}\text{O}_{\text{7}}^{\text{6-}}$ with the hexavalent group \[\text{ }-({{\text{O}}_{\text{3}}}\text{Si-O-Si}{{\text{O}}_{\text{3}}})-\] .
Pyrosilicate is formed by joining the two tetrahedral units$\text{ S}{{\text{i}}_{\text{2}}}\text{O}_{4}^{4-}$.this units joined together by the removal of oxygen and two units then join at the corners of oxygen atoms.
The structure of pyrosilicate is as follows:

One of the common examples of pyrosilicate is thortveitite. It is a scandium silicate yttrium silicate$\text{ (Sc,Y}{{\text{)}}_{\text{2}}}\text{S}{{\text{i}}_{\text{2}}}{{\text{O}}_{\text{7}}}$. It is a primary source of scandium.

Hence, (A) is the correct option.

Note: The silicon is a group 14 element and shows the allotropic properties. The
silicates have the silicon-oxide linkage but exist in a different structure. Students should remember the formulas for the silicates.