Answer
Verified
434.7k+ views
Hint: The different amines react differently with nitrous acid. Primary amines form alcohol. Secondary amines form nitroso compounds. The tertiary amine does not react. We can distinguish between both the compounds with the help of two reactions in presence of nitrous acid.
Complete step by step solution:
Ethylamine is a primary amine and ethyl methyl amine is a secondary amine. Both react differently with nitrous acid. So, this reaction is used for distinguished primary, secondary and tertiary amine compounds.
The product of the reaction of ethylamine with nitrous acid is shown as follows:
The reaction of ethylamine with nitrous acid gives ethanol, water and nitrogen gas. Nitrogen is colourless and odourless gas. By the evolution of the gas, primary amines are identified.
The product of reaction of ethyl methyl amine with nitrous acid is shown as follows:
The reaction of ethyl methyl amine with nitrous acid gives N-methyl-N-nitroso ethylamine and water. The N-methyl-N-nitroso ethanamine is yellow coloured oil. So, secondary amines are identified by the formation of a yellow oil.
Therefore, ethylamine forms ethanol and ethyl methyl amine forms nitrosamine with nitrous acid. So, both ethylamine and ethyl methyl amine can be distinguished by using nitrous acid as during the reaction of ethylamine, the evolution of the nitrogen gas observed and during the reaction of ethyl methyl amine, the yellow oily product forms.
Note: The tertiary amines do not react with nitrous acid. The amines are basic so, tertiary amine gets protonated in presence of nitrous acid and form cation of a tertiary amine. Thus by the reaction of an amine with nitrous acid, it can be identified that the amine is primary, secondary or tertiary. The nitrous acid is also used for the formation of diazonium salt of amines.
Complete step by step solution:
Ethylamine is a primary amine and ethyl methyl amine is a secondary amine. Both react differently with nitrous acid. So, this reaction is used for distinguished primary, secondary and tertiary amine compounds.
The product of the reaction of ethylamine with nitrous acid is shown as follows:
The reaction of ethylamine with nitrous acid gives ethanol, water and nitrogen gas. Nitrogen is colourless and odourless gas. By the evolution of the gas, primary amines are identified.
The product of reaction of ethyl methyl amine with nitrous acid is shown as follows:
The reaction of ethyl methyl amine with nitrous acid gives N-methyl-N-nitroso ethylamine and water. The N-methyl-N-nitroso ethanamine is yellow coloured oil. So, secondary amines are identified by the formation of a yellow oil.
Therefore, ethylamine forms ethanol and ethyl methyl amine forms nitrosamine with nitrous acid. So, both ethylamine and ethyl methyl amine can be distinguished by using nitrous acid as during the reaction of ethylamine, the evolution of the nitrogen gas observed and during the reaction of ethyl methyl amine, the yellow oily product forms.
Note: The tertiary amines do not react with nitrous acid. The amines are basic so, tertiary amine gets protonated in presence of nitrous acid and form cation of a tertiary amine. Thus by the reaction of an amine with nitrous acid, it can be identified that the amine is primary, secondary or tertiary. The nitrous acid is also used for the formation of diazonium salt of amines.
Recently Updated Pages
what is the correct chronological order of the following class 10 social science CBSE
Which of the following was not the actual cause for class 10 social science CBSE
Which of the following statements is not correct A class 10 social science CBSE
Which of the following leaders was not present in the class 10 social science CBSE
Garampani Sanctuary is located at A Diphu Assam B Gangtok class 10 social science CBSE
Which one of the following places is not covered by class 10 social science CBSE
Trending doubts
Which are the Top 10 Largest Countries of the World?
What percentage of the solar systems mass is found class 8 physics CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
The Equation xxx + 2 is Satisfied when x is Equal to Class 10 Maths
How do you graph the function fx 4x class 9 maths CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
Difference Between Plant Cell and Animal Cell
Why is there a time difference of about 5 hours between class 10 social science CBSE
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE