
How do you calculate the enthalpy change in the following reaction \[4N{H_3}\left( g \right) + 5{O_2}\left( g \right) \to 4NO\left( g \right) + 6{H_2}O\]?
Answer
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Hint: Enthalpy change of the response is characterized as the distinction of all out enthalpy change of the item and the absolute enthalpy change of the reactants. It is spoken to as. It is negative for exothermic responses and positive for endothermic responses.
Complete step by step answer:
At the point when a framework going through a compound response requires an inflow of the energy, the enthalpy of the absolute framework increments and when it emits a portion of its energy into the encompassing, the enthalpy of the complete framework diminishes. The piece of the energy of the particles that get used during a response is known as the inward enthalpy or the enthalpy controlled by the framework and the energy which isn't identified with the segments or substances going through response is known as the outside enthalpy or the enthalpy of the environmental factors.
For the given substance condition, the articulation for enthalpy change for this compound condition follows:
Consequently, the condition is given previously.
Total the \[\Delta H\] esteems for the products:
\[4NO{\text{ }} = {\text{ }}4{\text{ }}mol{\text{ x }}90.3{\text{ }}\dfrac{{kJ}}{{mol}}{\text{ }} = {\text{ }}361.2{\text{ }}kJ\]
\[6{H_2}O{\text{ }} = {\text{ }}6{\text{ }}mol{\text{ x (}} - {\text{ }}241.8){\text{ }} = {\text{ }} - {\text{ }}1450.8{\text{ }}kJ\]
\[\sum = - {\text{ }}1089.6kJ\]
Entirety the \[\Delta H\] esteems for the reactants:
\[4N{H_3} = {\text{ }}4mol{\text{ x (}} - 46.1{\text{ }}\dfrac{{kJ}}{{mol}}){\text{ }} = - {\text{ }}184.4{\text{ }}kJ\]
\[6{O_2}:{\text{ }}6{\text{ }}mol{\text{ x }}0{\text{ }} = {\text{ }}0{\text{ }}kJ\] (\[\Delta H\]for \[{O_2}\]is zero)
\[\sum {\text{ }} = {\text{ }} - {\text{ }}184.4{\text{ }}kJ\]
\[\Delta {H_{reaction}} = \sum \Delta {H_{products}}{\text{ }} - {\text{ }}\sum \Delta {H_{reac\tan ts}} = {\text{ }} - {\text{ }}1089.6{\text{ }}kJ{\text{ }} - {\text{ }}\left( { - {\text{ }}184.4{\text{ }}kJ} \right)\]
\[\Delta {H_{reaction}} = - {\text{ }}905.2{\text{ }}kJ\]
Note:
You can ascertain the standard enthalpy change of response by utilizing the standard enthalpies of development of the species that partake in the response, for example the reactants and the items. The adjustment in enthalpy is signified by \[\Delta H\].
Along these lines,
\[\Delta H{\text{ }} = {\text{ }}Potential{\text{ }}energy{\text{ }}of{\text{ }}product{\text{ }}-{\text{ }}Potential{\text{ }}energy{\text{ }}of{\text{ }}reactants\]
Complete step by step answer:
At the point when a framework going through a compound response requires an inflow of the energy, the enthalpy of the absolute framework increments and when it emits a portion of its energy into the encompassing, the enthalpy of the complete framework diminishes. The piece of the energy of the particles that get used during a response is known as the inward enthalpy or the enthalpy controlled by the framework and the energy which isn't identified with the segments or substances going through response is known as the outside enthalpy or the enthalpy of the environmental factors.
For the given substance condition, the articulation for enthalpy change for this compound condition follows:
Consequently, the condition is given previously.
Total the \[\Delta H\] esteems for the products:
\[4NO{\text{ }} = {\text{ }}4{\text{ }}mol{\text{ x }}90.3{\text{ }}\dfrac{{kJ}}{{mol}}{\text{ }} = {\text{ }}361.2{\text{ }}kJ\]
\[6{H_2}O{\text{ }} = {\text{ }}6{\text{ }}mol{\text{ x (}} - {\text{ }}241.8){\text{ }} = {\text{ }} - {\text{ }}1450.8{\text{ }}kJ\]
\[\sum = - {\text{ }}1089.6kJ\]
Entirety the \[\Delta H\] esteems for the reactants:
\[4N{H_3} = {\text{ }}4mol{\text{ x (}} - 46.1{\text{ }}\dfrac{{kJ}}{{mol}}){\text{ }} = - {\text{ }}184.4{\text{ }}kJ\]
\[6{O_2}:{\text{ }}6{\text{ }}mol{\text{ x }}0{\text{ }} = {\text{ }}0{\text{ }}kJ\] (\[\Delta H\]for \[{O_2}\]is zero)
\[\sum {\text{ }} = {\text{ }} - {\text{ }}184.4{\text{ }}kJ\]
\[\Delta {H_{reaction}} = \sum \Delta {H_{products}}{\text{ }} - {\text{ }}\sum \Delta {H_{reac\tan ts}} = {\text{ }} - {\text{ }}1089.6{\text{ }}kJ{\text{ }} - {\text{ }}\left( { - {\text{ }}184.4{\text{ }}kJ} \right)\]
\[\Delta {H_{reaction}} = - {\text{ }}905.2{\text{ }}kJ\]
Note:
You can ascertain the standard enthalpy change of response by utilizing the standard enthalpies of development of the species that partake in the response, for example the reactants and the items. The adjustment in enthalpy is signified by \[\Delta H\].
Along these lines,
\[\Delta H{\text{ }} = {\text{ }}Potential{\text{ }}energy{\text{ }}of{\text{ }}product{\text{ }}-{\text{ }}Potential{\text{ }}energy{\text{ }}of{\text{ }}reactants\]
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