Answer
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Hint: In this test the amines are treated with benzene sulfonyl chloride. Here amines act as nucleophiles which attack the electrophilic sulfonyl chloride. Now try and put together the reaction yourself.
Complete-step- by- step answer:
Hinsberg’s test is done to distinguish between primary, secondary and tertiary amines.
A German chemist named Oscar Heinrich Daniel Hinsberg gave this reaction in 1890.
The reagent used: known as Hinsberg’s reagent is benzene sulfonyl chloride (${C_6}{H_5}Cl{O_2}S$) which is an organosulfur compound. In this test the given amine is shaken with Hinsberg’s reagent in the presence of aqueous alkali which is either KOH or NaOH.
Now you might be thinking how to distinguish the amines using this reagent. So, to distinguish let us see the reactions of various amides with benzene sulfonyl chloride:
Primary amines ($R - N{H_2}$): When they react with Sulfonyl chloride it forms a sulfonamide salt which is soluble in alkali.
Secondary amines (${R_2} - NH$): When they react with sulfonyl chloride, it forms a sulfonamide salt which is insoluble in alkali.
Tertiary amines (${R_3}N$): They do not form any sulfonamide salt with sulfonyl chloride. Instead they cause the sulfonyl chloride to hydrolyse and form salts that are insoluble in water.
This is how Hinsberg’s test helps to differentiate between primary, secondary and tertiary amines by observing the difference in the solubility of the sulfonamide product in alkali.
Note: First draw the structures of primary, secondary and tertiary amines and also of benzene sulfonyl chloride properly. You should also keep in mind that in this test amine is acting as the nucleophile and sulfonyl chloride is acting as the electrophile. Do not get confused here.
Complete-step- by- step answer:
Hinsberg’s test is done to distinguish between primary, secondary and tertiary amines.
A German chemist named Oscar Heinrich Daniel Hinsberg gave this reaction in 1890.
The reagent used: known as Hinsberg’s reagent is benzene sulfonyl chloride (${C_6}{H_5}Cl{O_2}S$) which is an organosulfur compound. In this test the given amine is shaken with Hinsberg’s reagent in the presence of aqueous alkali which is either KOH or NaOH.
Now you might be thinking how to distinguish the amines using this reagent. So, to distinguish let us see the reactions of various amides with benzene sulfonyl chloride:
Primary amines ($R - N{H_2}$): When they react with Sulfonyl chloride it forms a sulfonamide salt which is soluble in alkali.
Secondary amines (${R_2} - NH$): When they react with sulfonyl chloride, it forms a sulfonamide salt which is insoluble in alkali.
Tertiary amines (${R_3}N$): They do not form any sulfonamide salt with sulfonyl chloride. Instead they cause the sulfonyl chloride to hydrolyse and form salts that are insoluble in water.
This is how Hinsberg’s test helps to differentiate between primary, secondary and tertiary amines by observing the difference in the solubility of the sulfonamide product in alkali.
Note: First draw the structures of primary, secondary and tertiary amines and also of benzene sulfonyl chloride properly. You should also keep in mind that in this test amine is acting as the nucleophile and sulfonyl chloride is acting as the electrophile. Do not get confused here.
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