Do the following conversions in not more than two steps:
Propanoic acid to 2-hydroxypropanoic acid
Answer
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Hint: We know that propanoic acid is a carboxylic acid. Carboxylic acid contains a carboxyl functional group. We have to know that the carboxyl functional group has a carbonyl functional group and a hydroxyl functional group. The carbonyl functional group is $ - CO$ and the hydroxyl functional group is $ - OH$. The general formula of carboxylic acid is $R - COOH$.
Complete step by step answer:
In the propanoic acid, there would be three atoms of carbon and in carbon first, the carboxyl functional group could be present.
In 2-hydroxypropanoic acid, a hydroxyl group could be present in the carbon second position of the parent carboxylic acid chain.
We can draw the structure of propanoic acid as,
We can draw the structure of 2-hydroxypropanoic acid is,
We can convert propanoic acid to 2-hydroxypropanoic acid by alpha halogenation reaction.
Propanoic acid is reacted with halogen such as chlorine, bromine in the presence of red phosphorus. We obtain alpha-halo carboxylic acid. This reaction is called the Hell Vohlard Zelinsky reaction. This alpha-halo carboxylic acid undergoes hydrolysis to form 2-hydroxypropanoic acid.
In the first step, propanoic acid is reacted with bromine in the presence of red phosphorus to form alpha-bromo carboxylic acid. The formed alpha-bromo carboxylic acid undergoes hydrolysis to form 2-hydroxypropanoic acid.
We can write the first step of this reaction as,
We can write the second step of this reaction as,
Note:
We have to know that the Hell Vohlard Zelinsky reaction is a reaction that is utilized for halogenation of carboxylic acid at the position of alpha carbon. Certain carboxylic acids and derivatives of acid like anhydrides (or) acyl halides could be halogenated during the absence of a catalyst. Iodination and fluorination of carboxylic acids could be accomplished by Hell Vohlard Zelinsky reaction.
Complete step by step answer:
In the propanoic acid, there would be three atoms of carbon and in carbon first, the carboxyl functional group could be present.
In 2-hydroxypropanoic acid, a hydroxyl group could be present in the carbon second position of the parent carboxylic acid chain.
We can draw the structure of propanoic acid as,
We can draw the structure of 2-hydroxypropanoic acid is,
We can convert propanoic acid to 2-hydroxypropanoic acid by alpha halogenation reaction.
Propanoic acid is reacted with halogen such as chlorine, bromine in the presence of red phosphorus. We obtain alpha-halo carboxylic acid. This reaction is called the Hell Vohlard Zelinsky reaction. This alpha-halo carboxylic acid undergoes hydrolysis to form 2-hydroxypropanoic acid.
In the first step, propanoic acid is reacted with bromine in the presence of red phosphorus to form alpha-bromo carboxylic acid. The formed alpha-bromo carboxylic acid undergoes hydrolysis to form 2-hydroxypropanoic acid.
We can write the first step of this reaction as,
We can write the second step of this reaction as,
Note:
We have to know that the Hell Vohlard Zelinsky reaction is a reaction that is utilized for halogenation of carboxylic acid at the position of alpha carbon. Certain carboxylic acids and derivatives of acid like anhydrides (or) acyl halides could be halogenated during the absence of a catalyst. Iodination and fluorination of carboxylic acids could be accomplished by Hell Vohlard Zelinsky reaction.
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