
Does benzoquinone show tautomerism?
Answer
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Hint: The phenomenon in which different compounds having the same chemical formula but they have different structures is isomerism, and those compounds are known as isomers, and this is an important phenomenon for compounds. Some types of isomerism are Positional isomerism, chain isomerism, tautomerism, functional isomerism, etc.
Complete step by step answer: - The isomers in functional differ with respect to the nature of the functional groups and hence belong to different families.
- Tautomers are actually functional isomers. They exist simultaneously and also in dynamic equilibrium. There are many types of tautomerism and keto-enol tautomerism is very common among them. - This tautomerism arises due to 1,3 migration of the hydrogen atom from carbon to oxygen atom and vice versa. For example,
- If the compound has alpha-hydrogen atom in the compound, only then the compound can show the keto-enol tautomerism because it is a necessary condition.
- Now for the question, the structure of benzoquinone is
- As we can clearly see that there is no presence of alpha hydrogen in the structure shown above. Thus, benzoquinone does not show tautomerism.
Additional information: As per the rule of keto-enol tautomerism, the hydroxy; group in all alcohols is attached directly with a double-bonded carbon atom, and forms aldehydes or ketones.
Note: It is important to note that an aldehyde or ketone shows tautomerism only when there is a presence of alpha hydrogen. The alpha hydrogen involved in 1,3 migration. Another example of a compound that doesn’t show tautomerism is benzaldehyde.
Complete step by step answer: - The isomers in functional differ with respect to the nature of the functional groups and hence belong to different families.
- Tautomers are actually functional isomers. They exist simultaneously and also in dynamic equilibrium. There are many types of tautomerism and keto-enol tautomerism is very common among them. - This tautomerism arises due to 1,3 migration of the hydrogen atom from carbon to oxygen atom and vice versa. For example,

- If the compound has alpha-hydrogen atom in the compound, only then the compound can show the keto-enol tautomerism because it is a necessary condition.
- Now for the question, the structure of benzoquinone is

- As we can clearly see that there is no presence of alpha hydrogen in the structure shown above. Thus, benzoquinone does not show tautomerism.
Additional information: As per the rule of keto-enol tautomerism, the hydroxy; group in all alcohols is attached directly with a double-bonded carbon atom, and forms aldehydes or ketones.
Note: It is important to note that an aldehyde or ketone shows tautomerism only when there is a presence of alpha hydrogen. The alpha hydrogen involved in 1,3 migration. Another example of a compound that doesn’t show tautomerism is benzaldehyde.
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