Courses
Courses for Kids
Free study material
Offline Centres
More
Store Icon
Store
seo-qna
SearchIcon
banner

How do you find the coordination number of sodium chloride (NaCl)?

Answer
VerifiedVerified
431.4k+ views
like imagedislike image
Hint: The crystal lattice of any molecule is the three – dimensional arrangement of its atoms. In a crystal, the arrangement of atoms is in a way that some atoms surround others. The number of atoms surrounding each atom is a coordination number of that atom. The lattice type of NaCl is Face centered cubic cell.

Complete answer:
The coordination number of any atom is defined as the number of atoms surrounding that atom in its crystal lattice structure. A unit cell is the smallest part of a crystal. A crystal lattice consists of various lattice points, these points are the ions or atoms of the molecule. Unit cells are of primitive (simple) and centered unit types that have FCC, BCC, and ECC.
We have NaCl which is an ionic solid. It is formed in the stoichiometric ratio of 1 : 1 as, 1 sodium atom Na+ is needed for combining by transferring the valence electron to 1 chlorine atom as Cl. This means this cation and anion is situated in the same number and has the same number of ions attached to each of them. As the unit cell of NaCl is FCC, which means that an ion is present at the four corners, and at the 6 faces of the lattice, as the structure of FCC suggests as follows,
seo images

This implies that one Na+ or Cl ion will be surrounded by ions that are above, below, in the front, at the back, at the right and at the left that makes a total of 6 ions. This means that in NaCl, Na+is surrounded by 6Cl ions and Cl is surrounded by 6Na+ ions.
Hence, the coordination number of sodium chloride NaCl is 6.

Note:
The 1 : 1 stoichiometry makes it possess the same coordination number for both atoms. The other unit cells include, BCC that is body centered cell, which has particles at the corners and one at the center. While, ECC called end centered cell has particles on corners and at the two opposite faces.
Latest Vedantu courses for you
Grade 11 Science PCM | CBSE | SCHOOL | English
CBSE (2025-26)
calendar iconAcademic year 2025-26
language iconENGLISH
book iconUnlimited access till final school exam
tick
School Full course for CBSE students
PhysicsPhysics
ChemistryChemistry
MathsMaths
₹41,848 per year
Select and buy