Answer
398.4k+ views
Hint: We know that nucleophilic substitution reaction is the reaction in which a nucleophile attacks an electrophile (positively charged) to replace a leaving group. A nucleophile is an electron rich species and an electrophile is an electron deficient species.
Complete step by step answer:
We know that the nitro group is an electron withdrawing group. When a nitro group is present at ortho and para position, it can withdraw electrons from the benzene ring. This facilitates the attack of nucleophiles on haloarene. The carbanion formed due to the attack of the nucleophile got stabilized by resonance. The negative charge appeared at the ortho and para position with respect to the halogen atom is stabilized by the nitro group.
Let’s understand with the help of a diagram.
Here, one of the resonating structures possess a negative charge on the carbon atom bonded to the nitro group. So, the negative charge stabilized.
Similarly in case of ortho-nitrobenzene,
Here, one of the resonating structures possesses negative charge on the carbon atom bonded to the nitro group. So, the negative charge is stabilized. And hence, the reactivity of haloarenes towards the nucleophilic substitution increases if the nitro group is present at ortho and meta position.
Note: In case meta-nitrobenzene, none of the resonating structures possesses the negative charge on the carbon atom which is bonded to the nitro group. Therefore, nitro group at meta position does not stabilize the negative charge and therefore no effect of nitro group on reactivity is found in case of meta nitrobenzene.
Complete step by step answer:
We know that the nitro group is an electron withdrawing group. When a nitro group is present at ortho and para position, it can withdraw electrons from the benzene ring. This facilitates the attack of nucleophiles on haloarene. The carbanion formed due to the attack of the nucleophile got stabilized by resonance. The negative charge appeared at the ortho and para position with respect to the halogen atom is stabilized by the nitro group.
Let’s understand with the help of a diagram.
![seo images](https://www.vedantu.com/question-sets/726bf844-c6b3-4f6b-a84f-3e5c09a2e6e97662180762645007156.png)
Here, one of the resonating structures possess a negative charge on the carbon atom bonded to the nitro group. So, the negative charge stabilized.
Similarly in case of ortho-nitrobenzene,
![seo images](https://www.vedantu.com/question-sets/5079edb5-67c2-44b5-afcc-96108707dd508750549531348735454.png)
Here, one of the resonating structures possesses negative charge on the carbon atom bonded to the nitro group. So, the negative charge is stabilized. And hence, the reactivity of haloarenes towards the nucleophilic substitution increases if the nitro group is present at ortho and meta position.
Note: In case meta-nitrobenzene, none of the resonating structures possesses the negative charge on the carbon atom which is bonded to the nitro group. Therefore, nitro group at meta position does not stabilize the negative charge and therefore no effect of nitro group on reactivity is found in case of meta nitrobenzene.
![seo images](https://www.vedantu.com/question-sets/073c17f3-0989-4e2f-a3e3-1bb27e5cba919202293143844186896.png)
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