Answer
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Hint: The reactant alkyne reacts with ${H_2}O$ in presence of \[HgS{O_4}/{H_2}S{O_4}\] and forms a product. So, we have to think about the reaction in which alkyne reacts with ${H_2}O$ in presence of \[HgS{O_4}/{H_2}S{O_4}\] and then tautomerism because the compound ( $ \rightleftharpoons $ this sign shows that this compound is tautomerising itself) is changing itself.
Complete answer:
So, we have to start with the reaction in which alkyne reacts with ${H_2}O$ in presence of \[HgS{O_4}/{H_2}S{O_4}\]. So, that reaction is Alkyne Hydration.
Alkyne hydration:
So, we try to learn these reaction with an example,
So, let’s take an example,
$C{H_3} - C \equiv C - H + {H_2}O \to C{H_3}COC{H_3}$
Mechanism:
So, in case of unsymmetrical alkynes, the addition of water in the alkyne in according to the Markovnikov’s Rule, which states that the $O - $ atom will attach with the carbon having less number of $H - $ atoms and the two $H - $ atoms will attach with the carbon having greater number of $H - $ atoms.
But In these cases, the alkyne is symmetric.
So, we don’t have to follow any Markovnikov’s Rule,
And the reaction will be,
$H - C \equiv C - H\xrightarrow[{HgS{O_4}/{H_2}S{O_4}}]{{{H_2}O}}C{H_3}CHO$
Now, the $C{H_3}CHO$ will tautomerise itself,
So, let’s talk about tautomerism,
Tautomerism: When an aldehyde having one hydrogen atom, adjacent to the carbonyl group (i.e, \[\alpha \] carbon), this hydrogen can move to the oxygen atom of the carbonyl group and the double bond between the carbonyl group is shifted to the adjacent to the carbonyl group (i.e, \[\alpha \] carbon). This type of movement of bonds is called tautomerism and the compounds are called tautomers.
So, $C{H_3}CHO$ will tautomerise itself as
Hence, the complete reaction will be
${C_2}{H_2}\xrightarrow[{HgS{O_4}/{H_2}S{O_4}}]{{{H_2}O}}C{H_2} = CHOH \rightleftharpoons C{H_3}CHO$
Hence, the correct option is (D) $LiF$.
Note: While alkyne is reacting with ${H_2}O$ in presence of \[HgS{O_4}/{H_2}S{O_4}\] , we have to use the Markovnikov’s Rule when the alkyne is un-symmetric and when \[\alpha \] carbon is present, we must have to think once about the tautomerism.
Complete answer:
So, we have to start with the reaction in which alkyne reacts with ${H_2}O$ in presence of \[HgS{O_4}/{H_2}S{O_4}\]. So, that reaction is Alkyne Hydration.
Alkyne hydration:
So, we try to learn these reaction with an example,
So, let’s take an example,
$C{H_3} - C \equiv C - H + {H_2}O \to C{H_3}COC{H_3}$
Mechanism:
![seo images](https://www.vedantu.com/question-sets/8befb78a-5eec-4417-b545-c822635db07d8014302803613021159.png)
So, in case of unsymmetrical alkynes, the addition of water in the alkyne in according to the Markovnikov’s Rule, which states that the $O - $ atom will attach with the carbon having less number of $H - $ atoms and the two $H - $ atoms will attach with the carbon having greater number of $H - $ atoms.
But In these cases, the alkyne is symmetric.
So, we don’t have to follow any Markovnikov’s Rule,
And the reaction will be,
$H - C \equiv C - H\xrightarrow[{HgS{O_4}/{H_2}S{O_4}}]{{{H_2}O}}C{H_3}CHO$
Now, the $C{H_3}CHO$ will tautomerise itself,
So, let’s talk about tautomerism,
Tautomerism: When an aldehyde having one hydrogen atom, adjacent to the carbonyl group (i.e, \[\alpha \] carbon), this hydrogen can move to the oxygen atom of the carbonyl group and the double bond between the carbonyl group is shifted to the adjacent to the carbonyl group (i.e, \[\alpha \] carbon). This type of movement of bonds is called tautomerism and the compounds are called tautomers.
So, $C{H_3}CHO$ will tautomerise itself as
![seo images](https://www.vedantu.com/question-sets/a052e2ab-93f4-4d78-b65f-faccd7f867077476246902889692476.png)
Hence, the complete reaction will be
${C_2}{H_2}\xrightarrow[{HgS{O_4}/{H_2}S{O_4}}]{{{H_2}O}}C{H_2} = CHOH \rightleftharpoons C{H_3}CHO$
Hence, the correct option is (D) $LiF$.
Note: While alkyne is reacting with ${H_2}O$ in presence of \[HgS{O_4}/{H_2}S{O_4}\] , we have to use the Markovnikov’s Rule when the alkyne is un-symmetric and when \[\alpha \] carbon is present, we must have to think once about the tautomerism.
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