Answer
Verified
465.3k+ views
Hint: Inorganic graphite is an inorganic compound whose structure is like graphite with alternating atoms replacing the carbon atoms in hexagonal structure.
Complete step by step answer:
Boron nitride is sometimes referred to as ‘inorganic graphite’ because its structure is like graphite with alternating boron and nitrogen atoms replacing the carbon atoms in the hexagonal structure.
$BN$ is isoelectronic to a similarly structured carbon lattice and thus exists in various crystalline forms.
The structure of $BN$ is
Figure-The structure of Boron Nitride
Additional information:
Boron nitride is produced synthetically. Hexagonal boron nitride is obtained by the reacting trioxide $\left( {{B_2}{O_3}} \right)$ or boric acid $\left( {{H_3}B{O_3}} \right)$ with ammonia ${\left( {NH} \right)_3}$ or $\left( {N{H_2}CON{H_2}} \right)$ in a nitrogen atmosphere.
${B_2}{O_3} + 2N{H_3} \to 2BN + 3{H_2}O$ $\left( {T = 900^\circ c} \right)$
$B{\left( {OH} \right)_3} + N{H_3} \to BN + 3{H_2}O$ $\left( {T = 900^\circ c} \right)$
${B_2}{O_3} + CO{\left( {N{H_2}} \right)_2} \to 2BN + C{O_2} + 2{H_2}O$ $\left( {T > 1000^\circ c} \right)$
${B_2}{O_3} + 3Ca{B_6} + IO{N_2} \to 2OBN + 3CaO$ $\left( {T > 1500^\circ c} \right)$
Similar to graphite, various molecules such as $N{H_3}$ or alkali metals can be intercalated into hexagonal boron nitride, that is inserted between its layers. Both experiment and theory suggest the intercalation is much more difficult for $BN$ than for graphite.
Note:
$BN$ is the most widely used polymorph. It is a good lubricant at both low and high temperature. $BN$ is used as an lubricant when electrical conductivity or chemical reactivity of graphite would be problematic.
Complete step by step answer:
Boron nitride is sometimes referred to as ‘inorganic graphite’ because its structure is like graphite with alternating boron and nitrogen atoms replacing the carbon atoms in the hexagonal structure.
$BN$ is isoelectronic to a similarly structured carbon lattice and thus exists in various crystalline forms.
The structure of $BN$ is
Figure-The structure of Boron Nitride
Additional information:
Boron nitride is produced synthetically. Hexagonal boron nitride is obtained by the reacting trioxide $\left( {{B_2}{O_3}} \right)$ or boric acid $\left( {{H_3}B{O_3}} \right)$ with ammonia ${\left( {NH} \right)_3}$ or $\left( {N{H_2}CON{H_2}} \right)$ in a nitrogen atmosphere.
${B_2}{O_3} + 2N{H_3} \to 2BN + 3{H_2}O$ $\left( {T = 900^\circ c} \right)$
$B{\left( {OH} \right)_3} + N{H_3} \to BN + 3{H_2}O$ $\left( {T = 900^\circ c} \right)$
${B_2}{O_3} + CO{\left( {N{H_2}} \right)_2} \to 2BN + C{O_2} + 2{H_2}O$ $\left( {T > 1000^\circ c} \right)$
${B_2}{O_3} + 3Ca{B_6} + IO{N_2} \to 2OBN + 3CaO$ $\left( {T > 1500^\circ c} \right)$
Similar to graphite, various molecules such as $N{H_3}$ or alkali metals can be intercalated into hexagonal boron nitride, that is inserted between its layers. Both experiment and theory suggest the intercalation is much more difficult for $BN$ than for graphite.
Note:
$BN$ is the most widely used polymorph. It is a good lubricant at both low and high temperature. $BN$ is used as an lubricant when electrical conductivity or chemical reactivity of graphite would be problematic.
Recently Updated Pages
A wire of length L and radius r is clamped rigidly class 11 physics JEE_Main
For which of the following reactions H is equal to class 11 chemistry JEE_Main
For the redox reaction MnO4 + C2O42 + H + to Mn2 + class 11 chemistry JEE_Main
In the reaction 2FeCl3 + H2S to 2FeCl2 + 2HCl + S class 11 chemistry JEE_Main
One mole of a nonideal gas undergoes a change of state class 11 chemistry JEE_Main
A stone is projected with speed 20 ms at angle 37circ class 11 physics JEE_Main
Trending doubts
Which is the longest day and shortest night in the class 11 sst CBSE
Who was the Governor general of India at the time of class 11 social science CBSE
Why is steel more elastic than rubber class 11 physics CBSE
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Define the term system surroundings open system closed class 11 chemistry CBSE
State and prove Bernoullis theorem class 11 physics CBSE