Answer
404.4k+ views
Hint: Basically, in case to o-nitrophenol, there is intramolecular hydrogen bonding whereas in case of p-nitrophenol there is intermolecular hydrogen bonding. Moreover, intramolecular hydrogen bonding occurs when two functional groups of a molecule can form hydrogen bonds with each other.
Complete step by step answer:
Nitro phenols are the compounds of the formula $HO{C_6}{H_{5 - X}}{(N{O_2})_X}$ . These are more acidic than phenol. Further, there are three isomeric nitro phenols which are listed below.
a)o-nitrophenol
b)m-nitrophenol
c)p-nitrophenol
Now, o-nitrophenol also known as 2- nitrophenol is a light-yellow solid with a peculiar sweet smell whereas p-nitrophenol or 4 nitrophenol is a colorless to light yellow solid with very little odor.2-Nitrophenol is a member in which one of the hydrogens that is ortho to hydroxyl group has been replaced by a nitro group. Their structures are as shown:
So, basically o-nitrophenol is steam volatile whereas p-nitrophenol has a higher boiling point. This is because o-nitrophenol has intermolecular hydrogen bonding leading to less association between adjacent molecules and hence lower boiling point whereas in case of p-nitrobenzene there is intermolecular hydrogen bonding which leads to more association. This further requires more energy to break the hydrogen bonds and thus leading to higher boiling point.
Note: Nitro phenols are poisonous in nature. They generally contaminate the soil near fabric factories and military plants. They should be handled with care to avoid any serious circumstance. Moreover, inhalation or ingestion may cause headache, nausea, blue color in lips and ears, drowsiness, cyanosis and eye irritation.
Complete step by step answer:
Nitro phenols are the compounds of the formula $HO{C_6}{H_{5 - X}}{(N{O_2})_X}$ . These are more acidic than phenol. Further, there are three isomeric nitro phenols which are listed below.
a)o-nitrophenol
b)m-nitrophenol
c)p-nitrophenol
Now, o-nitrophenol also known as 2- nitrophenol is a light-yellow solid with a peculiar sweet smell whereas p-nitrophenol or 4 nitrophenol is a colorless to light yellow solid with very little odor.2-Nitrophenol is a member in which one of the hydrogens that is ortho to hydroxyl group has been replaced by a nitro group. Their structures are as shown:
![seo images](https://www.vedantu.com/question-sets/2da9f081-c06c-4cdf-98c1-d10667fd5e778928125609488453874.png)
![seo images](https://www.vedantu.com/question-sets/5ec4f325-d26f-435a-9116-2bbdf6fa94734913314816423387294.png)
So, basically o-nitrophenol is steam volatile whereas p-nitrophenol has a higher boiling point. This is because o-nitrophenol has intermolecular hydrogen bonding leading to less association between adjacent molecules and hence lower boiling point whereas in case of p-nitrobenzene there is intermolecular hydrogen bonding which leads to more association. This further requires more energy to break the hydrogen bonds and thus leading to higher boiling point.
Note: Nitro phenols are poisonous in nature. They generally contaminate the soil near fabric factories and military plants. They should be handled with care to avoid any serious circumstance. Moreover, inhalation or ingestion may cause headache, nausea, blue color in lips and ears, drowsiness, cyanosis and eye irritation.
Recently Updated Pages
In a flask the weight ratio of CH4g and SO2g at 298 class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
In a flask colourless N2O4 is in equilibrium with brown class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
In a first order reaction the concentration of the class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
In a first order reaction the concentration of the class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
In a fermentation tank molasses solution is mixed with class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
In a face centred cubic unit cell what is the volume class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Trending doubts
Which are the Top 10 Largest Countries of the World?
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference Between Plant Cell and Animal Cell
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Give 10 examples for herbs , shrubs , climbers , creepers
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Change the following sentences into negative and interrogative class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Write a letter to the principal requesting him to grant class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Name 10 Living and Non living things class 9 biology CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Black foot disease is caused by the pollution of groundwater class 12 biology CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)