Answer
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Hint: Basically, in case to o-nitrophenol, there is intramolecular hydrogen bonding whereas in case of p-nitrophenol there is intermolecular hydrogen bonding. Moreover, intramolecular hydrogen bonding occurs when two functional groups of a molecule can form hydrogen bonds with each other.
Complete step by step answer:
Nitro phenols are the compounds of the formula $HO{C_6}{H_{5 - X}}{(N{O_2})_X}$ . These are more acidic than phenol. Further, there are three isomeric nitro phenols which are listed below.
a)o-nitrophenol
b)m-nitrophenol
c)p-nitrophenol
Now, o-nitrophenol also known as 2- nitrophenol is a light-yellow solid with a peculiar sweet smell whereas p-nitrophenol or 4 nitrophenol is a colorless to light yellow solid with very little odor.2-Nitrophenol is a member in which one of the hydrogens that is ortho to hydroxyl group has been replaced by a nitro group. Their structures are as shown:
So, basically o-nitrophenol is steam volatile whereas p-nitrophenol has a higher boiling point. This is because o-nitrophenol has intermolecular hydrogen bonding leading to less association between adjacent molecules and hence lower boiling point whereas in case of p-nitrobenzene there is intermolecular hydrogen bonding which leads to more association. This further requires more energy to break the hydrogen bonds and thus leading to higher boiling point.
Note: Nitro phenols are poisonous in nature. They generally contaminate the soil near fabric factories and military plants. They should be handled with care to avoid any serious circumstance. Moreover, inhalation or ingestion may cause headache, nausea, blue color in lips and ears, drowsiness, cyanosis and eye irritation.
Complete step by step answer:
Nitro phenols are the compounds of the formula $HO{C_6}{H_{5 - X}}{(N{O_2})_X}$ . These are more acidic than phenol. Further, there are three isomeric nitro phenols which are listed below.
a)o-nitrophenol
b)m-nitrophenol
c)p-nitrophenol
Now, o-nitrophenol also known as 2- nitrophenol is a light-yellow solid with a peculiar sweet smell whereas p-nitrophenol or 4 nitrophenol is a colorless to light yellow solid with very little odor.2-Nitrophenol is a member in which one of the hydrogens that is ortho to hydroxyl group has been replaced by a nitro group. Their structures are as shown:
So, basically o-nitrophenol is steam volatile whereas p-nitrophenol has a higher boiling point. This is because o-nitrophenol has intermolecular hydrogen bonding leading to less association between adjacent molecules and hence lower boiling point whereas in case of p-nitrobenzene there is intermolecular hydrogen bonding which leads to more association. This further requires more energy to break the hydrogen bonds and thus leading to higher boiling point.
Note: Nitro phenols are poisonous in nature. They generally contaminate the soil near fabric factories and military plants. They should be handled with care to avoid any serious circumstance. Moreover, inhalation or ingestion may cause headache, nausea, blue color in lips and ears, drowsiness, cyanosis and eye irritation.