Answer
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Hint :Benzene attached to a hydroxyl functional group is called phenol. Salicylic acid is a derivative of phenol itself with an additional carboxylic acid functional group attached to a position ortho to the hydroxyl group of phenol.
Complete Step By Step Answer:
Salicylic acid is an important industrial organic compound that can be derived from phenol through two different types of reactions. It contains the same structure as that of phenol with an additional carboxylic acid group $ (COOH) $ placed at the ortho position (adjacent position) of the hydroxyl group of phenol.
The two methods of converting phenol to salicylic acid are as follows:
Kolbe-Schmitt reaction: This reaction involves the conversion of acidic phenol into a phenoxide ion in presence of sodium hydroxide base. This is followed by the attack of phenoxide ion of the electrophilic carbon dioxide gas resulting in a carboxylate group getting attached at the ortho position. The reaction ends with a mild acidic hydrolysis that gives salicylic acid.
Thus it is a base facilitated carboxylation of phenol.
The overall reaction can be written as follows:
$ {\text{phenol}}\xrightarrow[{{H^ + }}]{\begin{subarray}{l}
NaOH \\
C{O_2}
\end{subarray} }{\text{salicylic acid}} $
Reimer–Tiemann reaction: This reaction involves the conversion of phenol to salicylic acid by treatment of phenol at high temperatures with carbon tetrachloride in the presence of an alkali followed by mild hydrolysis.
The reaction can be written as follows:
$ {\text{phenol}}\xrightarrow[{{H_2}O}]{\begin{subarray}{l}
NaOH \\
CC{l_4}
\end{subarray} }{\text{salicylic acid}} $
Note :
The Reimer–Tiemann reaction can be performed with both chloroform as well as carbon tetrachloride. The reaction in the presence of chloroform as a reagent gives salicylaldehyde, however that in the presence of carbon tetrachloride gives salicylic acid as the desired product.
Complete Step By Step Answer:
Salicylic acid is an important industrial organic compound that can be derived from phenol through two different types of reactions. It contains the same structure as that of phenol with an additional carboxylic acid group $ (COOH) $ placed at the ortho position (adjacent position) of the hydroxyl group of phenol.
The two methods of converting phenol to salicylic acid are as follows:
Kolbe-Schmitt reaction: This reaction involves the conversion of acidic phenol into a phenoxide ion in presence of sodium hydroxide base. This is followed by the attack of phenoxide ion of the electrophilic carbon dioxide gas resulting in a carboxylate group getting attached at the ortho position. The reaction ends with a mild acidic hydrolysis that gives salicylic acid.
Thus it is a base facilitated carboxylation of phenol.
The overall reaction can be written as follows:
$ {\text{phenol}}\xrightarrow[{{H^ + }}]{\begin{subarray}{l}
NaOH \\
C{O_2}
\end{subarray} }{\text{salicylic acid}} $
![seo images](https://www.vedantu.com/question-sets/f5f2a0c9-da36-411b-9268-28970a7fe65f8431645210734218171.png)
Reimer–Tiemann reaction: This reaction involves the conversion of phenol to salicylic acid by treatment of phenol at high temperatures with carbon tetrachloride in the presence of an alkali followed by mild hydrolysis.
The reaction can be written as follows:
$ {\text{phenol}}\xrightarrow[{{H_2}O}]{\begin{subarray}{l}
NaOH \\
CC{l_4}
\end{subarray} }{\text{salicylic acid}} $
![seo images](https://www.vedantu.com/question-sets/b6084c3c-d69f-4eec-bda1-fd48fedd49f5913325768077679611.png)
Note :
The Reimer–Tiemann reaction can be performed with both chloroform as well as carbon tetrachloride. The reaction in the presence of chloroform as a reagent gives salicylaldehyde, however that in the presence of carbon tetrachloride gives salicylic acid as the desired product.
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