
When phenol is treated with excess bromine water, it gives:
A.m-bromophenol
B.o- and p- bromophenol
C.2,4-dibromophenol
D.2,4,6-tribromophenol
Answer
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Hint:
Phenol is an organic compound that has an alcohol group attached to the benzene ring. Adding excess bromine water to the compound will result in Bromination and will give a white precipitate.
Complete step by step answer:
Phenol is an aromatic hydrocarbon, composed of benzene which has a hydroxyl group attached to it.
The alcohol group (-OH) in phenol is an activating group, i.e. it activates the ring by releasing electrons. Because of activation, the ring becomes very reactive. It is therefore, an ortho – para directing group. This is also known as 2,4-directing effect.
Bromination of phenol by excess bromine water will result in multiple substitution around the ring. This reaction is so feasible that it can take place in cold solvent in the absence of any catalyst.
The reaction can be represented as –
Therefore, the answer is – option (d) – When phenol is treated with excess bromine water, it gives 2,4,6-tribromophenol.
Additional Information: Bromine water is an indication test for phenol because the compound 2,4,6-tribromophenol is a white precipitate with an antiseptic smell.
Note:
If Bromination is done using a less polar solvent such as carbon disulfide, carbon tetrachloride, etc., it will give a monosubstituted compound – p-bromophenol, o-bromophenol is the minor product.
Phenol is an organic compound that has an alcohol group attached to the benzene ring. Adding excess bromine water to the compound will result in Bromination and will give a white precipitate.
Complete step by step answer:
Phenol is an aromatic hydrocarbon, composed of benzene which has a hydroxyl group attached to it.
The alcohol group (-OH) in phenol is an activating group, i.e. it activates the ring by releasing electrons. Because of activation, the ring becomes very reactive. It is therefore, an ortho – para directing group. This is also known as 2,4-directing effect.
Bromination of phenol by excess bromine water will result in multiple substitution around the ring. This reaction is so feasible that it can take place in cold solvent in the absence of any catalyst.
The reaction can be represented as –

Therefore, the answer is – option (d) – When phenol is treated with excess bromine water, it gives 2,4,6-tribromophenol.
Additional Information: Bromine water is an indication test for phenol because the compound 2,4,6-tribromophenol is a white precipitate with an antiseptic smell.
Note:
If Bromination is done using a less polar solvent such as carbon disulfide, carbon tetrachloride, etc., it will give a monosubstituted compound – p-bromophenol, o-bromophenol is the minor product.
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