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Hint: The reaction of phenols with carbon dioxide in the presence of alkalies is Kolbe–Schmitt reaction. It is a carboxylation reaction of phenols giving sodium phenoxide salts which on acidification give aromatic hydroxyl acids. These acids act as precursors for many industrially important compounds and aspirin is one of them.
Complete step by step answer:
Two different reactions are taking place here Kolbe–Schmitt reaction and esterification reaction (treatment of the product of Kolbe–Schmitt reaction with ${(C{H_3}CO)_2}O$ ester). The two reactions can be written as follows:
$1.$ Kolbe–Schmitt reaction: reaction of phenol with carbon dioxide in the presence of sodium hydroxide, followed by acidification converts phenol to $1 - $ hydroxybenzoic acid (Salicylic acid).
$2.$Esterification reaction: The salicylic acid is then reacted with acetic anhydride (${(C{H_3}CO)_2}O$) to form aspirin.
Hence, the correct answer is option ‘C’.
Additional information: Aspirin is an analgesic used to relieve pain during minor aches, cold and sometimes fever also. It is synthesized in industry by esterification of salicylic acid (which acts as precursor) with excess anhydride. The reaction is catalysed by the presence of small amounts of acid and the acetic acid formed as a side product is quenched by using small amounts of water. The Kolbe–Schmitt reaction or Kolbe process is carried out at very high pressure and temperature.
Note:
The reactions should be written and it is always better to remember the common names of some important compounds like salicylic acid, acetic anhydride and aspirin used in this reaction. These common names are generally used for commercially important compounds.
Complete step by step answer:
Two different reactions are taking place here Kolbe–Schmitt reaction and esterification reaction (treatment of the product of Kolbe–Schmitt reaction with ${(C{H_3}CO)_2}O$ ester). The two reactions can be written as follows:
$1.$ Kolbe–Schmitt reaction: reaction of phenol with carbon dioxide in the presence of sodium hydroxide, followed by acidification converts phenol to $1 - $ hydroxybenzoic acid (Salicylic acid).
$2.$Esterification reaction: The salicylic acid is then reacted with acetic anhydride (${(C{H_3}CO)_2}O$) to form aspirin.
Hence, the correct answer is option ‘C’.
Additional information: Aspirin is an analgesic used to relieve pain during minor aches, cold and sometimes fever also. It is synthesized in industry by esterification of salicylic acid (which acts as precursor) with excess anhydride. The reaction is catalysed by the presence of small amounts of acid and the acetic acid formed as a side product is quenched by using small amounts of water. The Kolbe–Schmitt reaction or Kolbe process is carried out at very high pressure and temperature.
Note:
The reactions should be written and it is always better to remember the common names of some important compounds like salicylic acid, acetic anhydride and aspirin used in this reaction. These common names are generally used for commercially important compounds.
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