Answer
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Hint: Silver nitrate in ammonia is actually Tollen’s reagent. It also reacts with acidic hydrogens to give precipitates.
Complete step by step answer:
To get the answer, let us check each reaction one by one:
Conc. \[{H_2}S{O_4}\]:
Propyne on reaction with conc. ${H_2}S{O_4}$ produces a ketone.
Propene on reaction with conc. ${{H}_{2}}S{{O}_{4}}$ produces alcohol.
Ketone and alcohol can’t be distinguished at this condition without adding any other reagent. Hence, it is not the correct option.
$B{r_2}] in [CC{l_4}$:
Propyne on reaction with $B{r_2}$ in $CC{l_4}$ produces a vicinal dibromo alkene whereas propene on reaction with $B{r_2}$ in $CC{l_4}$ produces a vicinal dibromo alkane.
Hence, the two compounds can’t be distinguished by this process.
Dil. $KMn{O_4}$:
Propynes on reaction with Dil. $KMn{O_4}$ produce -ketoacid.
Propene on reaction with Dil. $KMn{O_4}$ produce a vicinal diol.
Hence, the two compounds cannot be distinguished by this method also.
$AgN{O_3}$ in ammonia:
Propyne on reaction with $AgN{O_3}$ in ammonia produces a white precipitate, while propene does not show any reaction with the Tollen’s reagent.
This is due to the fact that Tollen’s reagent reacts with an acidic hydrogen forming a precipitate like in a propyne. The hydrogen which is replaced is very acidic due to high electronegativity of an sp hybridized carbon.
Hence, this reagent can be used to distinguish between a propyne and a propene.
Therefore, the correct answer is (D) $AgN{O_3}$ in ammonia.
Note: When an alkyne is reacted with conc. Sulphuric acid, ketone is formed by the Markovnikov addition of -OH, followed by the rearrangement of the alcohol formed from enol form to keto.
Complete step by step answer:
To get the answer, let us check each reaction one by one:
Conc. \[{H_2}S{O_4}\]:
Propyne on reaction with conc. ${H_2}S{O_4}$ produces a ketone.
$B{r_2}] in [CC{l_4}$:
Propyne on reaction with $B{r_2}$ in $CC{l_4}$ produces a vicinal dibromo alkene whereas propene on reaction with $B{r_2}$ in $CC{l_4}$ produces a vicinal dibromo alkane.
Dil. $KMn{O_4}$:
Propynes on reaction with Dil. $KMn{O_4}$ produce -ketoacid.
Propene on reaction with Dil. $KMn{O_4}$ produce a vicinal diol.
$AgN{O_3}$ in ammonia:
Propyne on reaction with $AgN{O_3}$ in ammonia produces a white precipitate, while propene does not show any reaction with the Tollen’s reagent.
This is due to the fact that Tollen’s reagent reacts with an acidic hydrogen forming a precipitate like in a propyne. The hydrogen which is replaced is very acidic due to high electronegativity of an sp hybridized carbon.
Hence, this reagent can be used to distinguish between a propyne and a propene.
Therefore, the correct answer is (D) $AgN{O_3}$ in ammonia.
Note: When an alkyne is reacted with conc. Sulphuric acid, ketone is formed by the Markovnikov addition of -OH, followed by the rearrangement of the alcohol formed from enol form to keto.
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