Answer
Verified
403.8k+ views
Hint: To answer this question, you must recall the reactions occurring when alkenes and alkynes are reacted with the given reagents in the compounds. The reaction in which only one of the hydrocarbons reacts selectively or compounds with different properties are formed or changes like change in colour, precipitation etc. are observed can be used to distinguish them. The test used is known as iodoform test.
Complete step by step solution
Treating with $ {\text{AgN}}{{\text{O}}_{\text{3}}} $ : When reacted with silver nitrate, silver halide is formed. We know that silver chloride is readily soluble in aqueous solution while silver iodide on the other hand is insoluble in water and forms a precipitate. Thus, we can use this method to distinguish between pure $ {\text{CHC}}{{\text{l}}_{\text{3}}} $ and pure $ {\text{CH}}{{\text{I}}_{\text{3}}} $ .
The correct answer is D.
Note
Litmus paper is used as an indicator for testing whether a given substance or solution is acidic or basic or neutral. Both chloroform and iodoform are neutral substances. They are neither acidic nor basic. There will be no change in the colour of litmus paper with either of the compounds. Thus, we cannot use this method for distinguishing pure $ {\text{CHC}}{{\text{l}}_{\text{3}}} $ and pure $ {\text{CH}}{{\text{I}}_{\text{3}}} $ .
On treatment with aq. $ {\text{KOH}} $ , the halide atoms are replaced by the hydroxyl groups one by one. All the three halogen atoms are replaced in both chloroform as well as iodoform. Three hydroxyl groups cannot co- exist on a single carbon atom. Thus the molecule undergoes loss of a water molecule to form formic acid. Aqueous potassium hydroxide is a strong base and thus reacts with the formic acid to give potassium formate. Thus, we cannot use this method for distinguishing pure $ {\text{CHC}}{{\text{l}}_{\text{3}}} $ and pure $ {\text{CH}}{{\text{I}}_{\text{3}}} $ .
Treating with $ {\text{HCl}} $ also doesn’t give any such visible changes that can help us distinguish.
Complete step by step solution
Treating with $ {\text{AgN}}{{\text{O}}_{\text{3}}} $ : When reacted with silver nitrate, silver halide is formed. We know that silver chloride is readily soluble in aqueous solution while silver iodide on the other hand is insoluble in water and forms a precipitate. Thus, we can use this method to distinguish between pure $ {\text{CHC}}{{\text{l}}_{\text{3}}} $ and pure $ {\text{CH}}{{\text{I}}_{\text{3}}} $ .
The correct answer is D.
Note
Litmus paper is used as an indicator for testing whether a given substance or solution is acidic or basic or neutral. Both chloroform and iodoform are neutral substances. They are neither acidic nor basic. There will be no change in the colour of litmus paper with either of the compounds. Thus, we cannot use this method for distinguishing pure $ {\text{CHC}}{{\text{l}}_{\text{3}}} $ and pure $ {\text{CH}}{{\text{I}}_{\text{3}}} $ .
On treatment with aq. $ {\text{KOH}} $ , the halide atoms are replaced by the hydroxyl groups one by one. All the three halogen atoms are replaced in both chloroform as well as iodoform. Three hydroxyl groups cannot co- exist on a single carbon atom. Thus the molecule undergoes loss of a water molecule to form formic acid. Aqueous potassium hydroxide is a strong base and thus reacts with the formic acid to give potassium formate. Thus, we cannot use this method for distinguishing pure $ {\text{CHC}}{{\text{l}}_{\text{3}}} $ and pure $ {\text{CH}}{{\text{I}}_{\text{3}}} $ .
Treating with $ {\text{HCl}} $ also doesn’t give any such visible changes that can help us distinguish.
Recently Updated Pages
How many sigma and pi bonds are present in HCequiv class 11 chemistry CBSE
Mark and label the given geoinformation on the outline class 11 social science CBSE
When people say No pun intended what does that mea class 8 english CBSE
Name the states which share their boundary with Indias class 9 social science CBSE
Give an account of the Northern Plains of India class 9 social science CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
Trending doubts
Difference Between Plant Cell and Animal Cell
Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
10 examples of evaporation in daily life with explanations
Write a letter to the principal requesting him to grant class 10 english CBSE
The Equation xxx + 2 is Satisfied when x is Equal to Class 10 Maths
Name 10 Living and Non living things class 9 biology CBSE