
How many sigma and pi bonds are in the HCN molecule?
Answer
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Hint: Hydrogen cyanide is an acid that has molecular formula . We know that when a pair of electrons are shared by two atoms, a covalent bond is formed. Sigma ( ) bonds and pi ( ) bonds are two types of covalent bonds.
Complete step by step solution:
The strongest type of covalent chemical bond is a sigma ( ) bond. A sigma ( ) bond is formed when the atomic orbitals overlap head-on. Usually, sigma ( ) bonds are single bonds.
The sigma ( ) bonds are symmetrical and can rotate about the bond axis. Some of the most common sigma bonds are s+s, , s+ , and . Here, s, p, and d are atomic orbitals and z is the bond axis.
Now, the covalent chemical bonds which are formed when the atomic orbitals overlap laterally are known as pi ( ) bonds. Usually, there is 1 pi ( ) bond in double bonds and 2 pi ( ) bonds in triple bonds.
Pi ( ) bonds cannot rotate about the bond axis without breaking the bond.
Now, in HCN, we can see that there are two single bonds, H-C and C-N, hence it has two sigma ( ) bonds. Whereas it has a triple bond in and hence has two pi ( ) bonds.
So, the HCN molecule has 2 sigma ( ) bonds and 2 pi ( ) bonds.
Additional Information: Some of the properties of HCN are
- It can be synthesized by combining ammonia and methane
- It has an odor of bitter almond oil.
- It exists in both the gaseous as well as the liquid state.
- It has a melting point of 259.86 K and a boiling point of 299.00 K.
- It has a density of 0.69 g/l.
- It has a linear structure.
- It is extremely toxic as well as poisonous in nature and has been used as chemical weapons.
- It is colorless and is soluble and miscible in water and ethanol.
Note: It should be noted that even though pi ( ) bonds are weaker than sigma ( ) bonds, but when atoms are bonded by both sigma ( ) bonds and pi ( ) bonds, their strength is greater than either of the bonds alone. Hence the strength of multiple bonds (double and triple bonds) is more than that of a single bond.
Complete step by step solution:
The strongest type of covalent chemical bond is a sigma (

The sigma (
Now, the covalent chemical bonds which are formed when the atomic orbitals overlap laterally are known as pi (

Pi (
Now, in HCN, we can see that there are two single bonds, H-C and C-N, hence it has two sigma (
So, the HCN molecule has 2 sigma (
Additional Information: Some of the properties of HCN are
- It can be synthesized by combining ammonia and methane
- It has an odor of bitter almond oil.
- It exists in both the gaseous as well as the liquid state.
- It has a melting point of 259.86 K and a boiling point of 299.00 K.
- It has a density of 0.69 g/l.
- It has a linear structure.
- It is extremely toxic as well as poisonous in nature and has been used as chemical weapons.
- It is colorless and is soluble and miscible in water and ethanol.
Note: It should be noted that even though pi (
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