Answer
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Hint: We shall draw the structure of acetone and then draw its enol tautomer. Looking at the structure, we can determine the number of sigma bonds, pi bonds and lone pairs of electrons.
Complete step by step answer:
In organic reactions, due to the acidic nature of hydrogens present on the alpha carbon of ketones (that is hydrogen attached to the carbon atom next to the functional group – keep in mind that the carbon atom present adjacent to the functional group is known as alpha carbon atom), a reactive intermediate called enol is formed. As the name suggests, enol contains “ene”-double bond and “ol”-alcohol. There will be a chemical equilibrium established between the ketone form and its enol form. This is known as keto-enol tautomerism.
We know that the IUPAC name of acetone is propan-2-one and it has the structural formula
It forms an enol as shown below
So the overall keto-enol tautomerism can be represented as
Now that we have the structure of the enol form, let us find the number of sigma and pi bonds and also the number of lone pairs of electrons. Just to recall, sigma bonds are the bond formed by axial overlap of atomic orbitals whereas pi bonds are formed by the lateral overlap. All the single bonds in the structure represent a sigma bond whereas the double bonds represent a pi bond.
Number of single bonds in the enol form of acetone is 9. Therefore there are 9 sigma bonds. Hence we can eliminate options (B) and (C). As you can observe in the structure, there is only one double bond which indicates the presence of one pi bond. So the correct answer is option (A). We can cross check the number of lone pairs of electrons as well. There are 2 lone pairs present on the oxygen atom.
Thus the correct answer is A).
Note: We know that a pi bond can be formed only after the formation of a sigma bond. So in a double bond, we should count one bond as sigma and the other as pi. Similarly, in a triple bond one bond will be sigma and the other two will be pi.
Complete step by step answer:
In organic reactions, due to the acidic nature of hydrogens present on the alpha carbon of ketones (that is hydrogen attached to the carbon atom next to the functional group – keep in mind that the carbon atom present adjacent to the functional group is known as alpha carbon atom), a reactive intermediate called enol is formed. As the name suggests, enol contains “ene”-double bond and “ol”-alcohol. There will be a chemical equilibrium established between the ketone form and its enol form. This is known as keto-enol tautomerism.
We know that the IUPAC name of acetone is propan-2-one and it has the structural formula
It forms an enol as shown below
So the overall keto-enol tautomerism can be represented as
Now that we have the structure of the enol form, let us find the number of sigma and pi bonds and also the number of lone pairs of electrons. Just to recall, sigma bonds are the bond formed by axial overlap of atomic orbitals whereas pi bonds are formed by the lateral overlap. All the single bonds in the structure represent a sigma bond whereas the double bonds represent a pi bond.
Number of single bonds in the enol form of acetone is 9. Therefore there are 9 sigma bonds. Hence we can eliminate options (B) and (C). As you can observe in the structure, there is only one double bond which indicates the presence of one pi bond. So the correct answer is option (A). We can cross check the number of lone pairs of electrons as well. There are 2 lone pairs present on the oxygen atom.
Thus the correct answer is A).
Note: We know that a pi bond can be formed only after the formation of a sigma bond. So in a double bond, we should count one bond as sigma and the other as pi. Similarly, in a triple bond one bond will be sigma and the other two will be pi.
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