Answer
Verified
378k+ views
Hint: To solve this question, we first need to know what benzoic acid, styrene, benzamide, and dry ice.
Benzoic acid: A colorless and crystalline derivative of benzene having formula ${{C}_{6}}{{H}_{5}}COOH$
Styrene: A colorless and oily derivative of benzene having formula ${{C}_{6}}{{H}_{5}}CH=C{{H}_{2}}$.
Benzamide: A white and solid derivative of benzoic acid having formula ${{C}_{6}}{{H}_{5}}C(O)N{{H}_{2}}$.
Dry ice: A cooling agent which is the solid form of the gas carbon dioxide $C{{O}_{2}}$.
Complete answer:
Let us look at the reactions involving the preparation of benzoic acid from styrene, benzamide, and dry ice.
a) Using styrene (phenylethane) to prepare benzoic acid.
While converting styrene to benzoic acid, an oxidizing agent is used.
Either potassium permanganate or potassium dichromate, in the presence of sulfuric acid, acts as a strong oxidizing agent and converts styrene to benzoic acid.
Styrene is first converted to potassium benzoate and then acidified to give benzoic acid.
The reaction proceeds as follows:
Along with benzoic acid, carbon dioxide $C{{O}_{2}}$ gas is released and a water ${{H}_{2}}O$ molecule is produced as by-products.
b) Using benzamide to prepare benzoic acid.
In the presence of an acid like dilute hydrochloric acid, the hydrolysis of benzamide with sodium hydroxide (NaOH) forms benzoic acid.
Benzamide is first converted to sodium benzoate which is further acidified to benzoic acid.
The reaction proceeds as follows:
Along with benzoic acid, ammonia $N{{H}_{3}}$ is released as the by-product.
c) Using dry ice to prepare benzoic acid.
When dry ice or solid carbon dioxide $C{{O}_{2}}$ is added to a solution of phenyl magnesium iodide in dry ether, an adduct is formed. The adduct formed is a magnesium salt of carboxylic acid.
When this adduct is hydrolyzed in the presence of an acid, it gives benzoic acid.
The reaction proceeds as follows:
Along with benzoic acid, magnesium hydroxide (MgOH) is formed as a by-product.
Note:
It should be noted that the gas released from dry ice can increase the levels of carbon dioxide $C{{O}_{2}}$ in the blood and can cause hypercapnia.
Also, styrene is considered to be carcinogenic and toxic, especially when in contact with skin or eyes.
Benzoic acid on the other hand is produced naturally in many plants and animal species.
Benzoic acid: A colorless and crystalline derivative of benzene having formula ${{C}_{6}}{{H}_{5}}COOH$
Styrene: A colorless and oily derivative of benzene having formula ${{C}_{6}}{{H}_{5}}CH=C{{H}_{2}}$.
Benzamide: A white and solid derivative of benzoic acid having formula ${{C}_{6}}{{H}_{5}}C(O)N{{H}_{2}}$.
Dry ice: A cooling agent which is the solid form of the gas carbon dioxide $C{{O}_{2}}$.
Complete answer:
Let us look at the reactions involving the preparation of benzoic acid from styrene, benzamide, and dry ice.
a) Using styrene (phenylethane) to prepare benzoic acid.
While converting styrene to benzoic acid, an oxidizing agent is used.
Either potassium permanganate or potassium dichromate, in the presence of sulfuric acid, acts as a strong oxidizing agent and converts styrene to benzoic acid.
Styrene is first converted to potassium benzoate and then acidified to give benzoic acid.
The reaction proceeds as follows:
Along with benzoic acid, carbon dioxide $C{{O}_{2}}$ gas is released and a water ${{H}_{2}}O$ molecule is produced as by-products.
b) Using benzamide to prepare benzoic acid.
In the presence of an acid like dilute hydrochloric acid, the hydrolysis of benzamide with sodium hydroxide (NaOH) forms benzoic acid.
Benzamide is first converted to sodium benzoate which is further acidified to benzoic acid.
The reaction proceeds as follows:
Along with benzoic acid, ammonia $N{{H}_{3}}$ is released as the by-product.
c) Using dry ice to prepare benzoic acid.
When dry ice or solid carbon dioxide $C{{O}_{2}}$ is added to a solution of phenyl magnesium iodide in dry ether, an adduct is formed. The adduct formed is a magnesium salt of carboxylic acid.
When this adduct is hydrolyzed in the presence of an acid, it gives benzoic acid.
The reaction proceeds as follows:
Along with benzoic acid, magnesium hydroxide (MgOH) is formed as a by-product.
Note:
It should be noted that the gas released from dry ice can increase the levels of carbon dioxide $C{{O}_{2}}$ in the blood and can cause hypercapnia.
Also, styrene is considered to be carcinogenic and toxic, especially when in contact with skin or eyes.
Benzoic acid on the other hand is produced naturally in many plants and animal species.
Recently Updated Pages
How many sigma and pi bonds are present in HCequiv class 11 chemistry CBSE
Mark and label the given geoinformation on the outline class 11 social science CBSE
When people say No pun intended what does that mea class 8 english CBSE
Name the states which share their boundary with Indias class 9 social science CBSE
Give an account of the Northern Plains of India class 9 social science CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
Trending doubts
Difference Between Plant Cell and Animal Cell
Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
10 examples of evaporation in daily life with explanations
Write a letter to the principal requesting him to grant class 10 english CBSE
The Equation xxx + 2 is Satisfied when x is Equal to Class 10 Maths
Name 10 Living and Non living things class 9 biology CBSE