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Rubber Processing

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What is Processing?

Rubber Processing Comprises Four Basic Steps: 

  1. Mastication, the first step, occurs when the elastomer is removed, and the molecules are broken down to provide a more effortless flow. 

  2. Mixing, the second step, is usually carried out immediately after the mastication process when additives are incorporated. 

  3. Shaping, the third step, occurs for the dense mass obtained, for example, either by extrusion or moulding.

  4. Curing, the final step, occurs when the polymer molecules become interlinked and the shape of the dense mass is fixed.

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Mastication

Mastication and softening are both steps that are usually carried out in batches. The operation of rubber is done either on rubber mills or in a large enclosed mixing machine. 


A prominent example of an enclosed machine is the Banbury, which is a registered trademark mixer. It comprises heavy steel counter-rotating paddles in an hourglass-shaped chamber and can hold up to a one-half ton of rubber.


Rubber mills usually hold two large horizontally opposed yet closely spaced steel cylinders, which are almost up to three meters or ten feet long. They are rotated slowly in opposite directions and at somewhat varied speeds. 


In the mastication process, the rubber is sheared and softened. This occurs between the wall of the Banbury mixer and the paddles. Another approach is between the two cylinders in the rolling mill.

Mixing

Mixing is a process carried out on machines similar to those used in the mastication process, sometimes immediately after softening. A few various kinds incorporated into the base elastomer by a combined mixing and shearing action are- reactive materials, protective chemicals, oils, and fillers. 

An enclosed Banbury-type mixer is known to produce up to one-half ton of the mixed compound within a few minutes. The compound is then sheeted out and coated with a soap release. This prevents the compound from sticking and then stored until used on the steel pallets that can hold up to one ton of rubber. 

Shaping

Shaping of the mixture into the desired form occurs in multiple ways. Extruders produce long and continuous products such as tire treads, wire coverings, and tubing in this step. Extruders are used to build several profiles that are cut to the actual length later. Multi-Roll calendars are commonly used to make wide sheeting.


In injection and transfer moulds, the rubber mix is enforced through the channels into a mould chamber to acquire the required shape, cured under immense pressure.

 

Rubber tires are composed of multiple components- sidewall compound, cord plies, bead wire, tread, inner liner, and belt package. These components are brought and assembled as a complete whole tire. This occurs before the transfer to the curing press.

Curing

Curing is the final process that is carried out in pressurized steel moulds. It is heated either by electricity or steam to the temperature at which the interlinking reaction takes place. 


The standard curing conditions are a few minutes at 160 °C (320 °F) temperature. Because heat penetrates slowly, thick articles must be allowed to cure for longer time intervals, several hours, and lower temperatures. 


The pressure of one megapascal or 145 pounds per square inch or more is customarily imposed to maintain the wanted shape. This forces the trapped air to dissolve in the compound. A few other methods of curing the rubber mix upon the compound that took shape include steam heating in autoclaves or microwave radiation or passage through a heated bath of molten metal salts or a fluidized bed. 


In these methods, the curing process is carried out at near atmospheric pressure.

What is Rubber Chemical Compound Processing?

The blending or compounding of polymers, specifically the elastomers, is done for two reasons. The first reason is to improve the base elastomer's technical properties and the second for an enhanced rubber chemical compound processing behaviour. 


Rubber compounding is a standard method that refers to adding specific chemicals to raw rubber material to obtain the desired properties. The well-known chemicals that are often used are cross-linking agents, colourants, and anti-degradants. 


The cross-linking agents must establish cross-linking agents to interconnect at the molecular level to improve elasticity and strength. 


During the vulcanization or curing process, the unformulated elastomers are linked together. They form networks, increasing the strength and modulus and decreasing the hysteresis. Sulphur is a joint and widely used rubber compounding agent.


Reclaimed rubber is a rubber compounding ingredient. The scrap rubber undergoes a unique process before it can be reused. The rubber obtained as the by-product in the process is known as reclaimed rubber.


Rubber compounding processes using carbon particles often involve intensive mechanical processing.

FAQs on Rubber Processing

1. What is Processing?

Ans: Rubber processing comprises the operations performed on the systems or materials to increase the utility of the material through a chemical reaction, flow, or permanent change in a physical property.


The most significant processing steps wherein most chemical changes occur in the tire production are- polymer breakdown by mastication in a Banbury or on a mill, extrusion, calendering, and curing. 


A tire building process and moulding in the curing operation do generally not involve chemical reactions.


Processing generally includes mixing, extrusion, and calendering of rubber compounds, containing oils, carbon blacks, and other organic and inorganic chemicals.

One product-tires dominate the rubber processing industry and rubber goods.

2. What is Vulcanization?

Ans: Vulcanisation creates either a synthetic or a natural rubber with a chemical agent, usually sulfur or a sulfur-containing compound, or a peroxide. This imparts improved properties, such as lower plasticity, more resistance to solvent action, and better elasticity.


However, a few of the rubber products are used in the unvulcanized state. Only a limited amount of rubber or rubber products goes into pure gum stocks. Therefore, the blending of rubbers either alone or in mixtures, with reinforcing fillers or agents, or cure systems must be carefully controlled to manufacture high-quality rubber products.


The classic procedure for compounding rubber during vulcanization is mixing the baled rubber on a mill or an enclosed mixer.