Answer
Verified
56.7k+ views
Hint: The coordination complexes that show linkage isomerism must have one special type of ligand which has two donor atoms, but only one of the donor atoms can bind to the central metal atom at a time.
Complete step by step solution:
- The coordination complexes that show linkage isomerism have ambidentate ligand.
- Ambidentate ligands are those which have two donor atoms, but only one of the donor atoms can bind to the central metal atom at a time.
- ‘Ambi’ means both and dentate means the denticity of the ligand.
- Denticity is the number of the donor atoms of the ligand that binds to the central metal atom in the coordination complex.
- Here, \[[Co{{(N{{H}_{3}})}_{5}}(N{{O}_{2}})]C{{l}_{2}}\]exhibits linkage isomerism.
\[N{{O}_{2}}\] is the ambidentate ligand in this coordination complex. This ligand is the reason the coordination complex shows the linkage isomerism.
When the central metal atom is bonded with nitrogen, the ligand is\[N{{O}_{2}}\]. When the metal atom is bonded with oxygen, the ligand is\[ONO\].
- Other examples of the ambidentate ligand are \[C{{N}^{-}}\]and\[N{{C}^{-}}\], \[SC{{N}^{-}}\]and\[NC{{S}^{-}}\].
- \[[Co{{(N{{H}_{3}})}_{5}}(N{{O}_{2}})]C{{l}_{2}}\]and \[[Co{{(N{{H}_{3}})}_{5}}(ONO)]C{{l}_{2}}\]are the linkage isomers.
So, option C is the correct option.
Additional Information:
Ligands can be monodentate, bidentate, and multidentate as well depending upon the number of the donor atoms of the ligand binding to the central metal atom.
Note \[N{{O}_{2}}\]is called a nitro ligand. When the donation is from the nitrogen to the metal center, it is nitro complex. The linkage of the ligand is as follow
\[ONO\]is called nitrito ligand. When the donation is from the nitrogen to the metal centre, it is nitrito complex. The linkage is as follows:
The complexes are octahedral in shape.
Complete step by step solution:
- The coordination complexes that show linkage isomerism have ambidentate ligand.
- Ambidentate ligands are those which have two donor atoms, but only one of the donor atoms can bind to the central metal atom at a time.
- ‘Ambi’ means both and dentate means the denticity of the ligand.
- Denticity is the number of the donor atoms of the ligand that binds to the central metal atom in the coordination complex.
- Here, \[[Co{{(N{{H}_{3}})}_{5}}(N{{O}_{2}})]C{{l}_{2}}\]exhibits linkage isomerism.
\[N{{O}_{2}}\] is the ambidentate ligand in this coordination complex. This ligand is the reason the coordination complex shows the linkage isomerism.
When the central metal atom is bonded with nitrogen, the ligand is\[N{{O}_{2}}\]. When the metal atom is bonded with oxygen, the ligand is\[ONO\].
- Other examples of the ambidentate ligand are \[C{{N}^{-}}\]and\[N{{C}^{-}}\], \[SC{{N}^{-}}\]and\[NC{{S}^{-}}\].
- \[[Co{{(N{{H}_{3}})}_{5}}(N{{O}_{2}})]C{{l}_{2}}\]and \[[Co{{(N{{H}_{3}})}_{5}}(ONO)]C{{l}_{2}}\]are the linkage isomers.
So, option C is the correct option.
Additional Information:
Ligands can be monodentate, bidentate, and multidentate as well depending upon the number of the donor atoms of the ligand binding to the central metal atom.
Note \[N{{O}_{2}}\]is called a nitro ligand. When the donation is from the nitrogen to the metal center, it is nitro complex. The linkage of the ligand is as follow
\[ONO\]is called nitrito ligand. When the donation is from the nitrogen to the metal centre, it is nitrito complex. The linkage is as follows:
The complexes are octahedral in shape.
Recently Updated Pages
Write a composition in approximately 450 500 words class 10 english JEE_Main
Arrange the sentences P Q R between S1 and S5 such class 10 english JEE_Main
What is the common property of the oxides CONO and class 10 chemistry JEE_Main
What happens when dilute hydrochloric acid is added class 10 chemistry JEE_Main
If four points A63B 35C4 2 and Dx3x are given in such class 10 maths JEE_Main
The area of square inscribed in a circle of diameter class 10 maths JEE_Main
Other Pages
Electric field due to uniformly charged sphere class 12 physics JEE_Main
The correct IUPAC name of the given compound is A isopropylbenzene class 11 chemistry JEE_Main
Explain the construction and working of a GeigerMuller class 12 physics JEE_Main
If a wire of resistance R is stretched to double of class 12 physics JEE_Main