
Chlorobutane on reaction with alcoholic potash gives: -
A)
B) Butanol
C)
D) Butanol
Answer
467.4k+ views
Hint: When alcoholic potash will react with an alkyl halide, elimination reaction will take place. Alcoholic potash is nothing but dissolved in alcohol, most preferably ethanol. Elimination reaction is the process by which organic compounds containing only single bonds (saturated compounds) are transformed to compounds containing double or triple bonds (unsaturated compounds). There are two types of elimination reaction: -
Complete solution:
As we already know that is reacting with an alkyl halide to form alkene as a product so we name this reaction as Dehydrohalogenation as in the mechanism of the reaction one halogen and one hydrogen will be removed from the compound. Here will act as a Dehydrohalogenating agent.
So, we write the reaction as: -
Here we see that elimination or elimination is taking place. In this case the removal of the halogen atom which in this case and removal of hydrogen atom attached to the carbon atom is taking place under the influence of highly basic metal hydroxide mixed with ethanol which is in this case. This process finally leads to the formation of alkene.
Let us see which is the carbon: -
So, the correct answer is Option A i.e.,
Additional information: Elimination reactions are commonly known by the kind of atoms or groups of atoms leaving the molecule. The removal of a hydrogen atom and a halogen atom is known as dehydrohalogenation. When both the leaving atoms are halogens then the reaction is known as dehalogenation. Similarly, the elimination of water molecules, usually from an alcohol, is known as dehydrogenation.
Note:Elimination reaction is an important method for the preparation of alkenes. Here Saytzeff product is the major product formed. According to Saytzeff rule, the negative part that is the halogen will be removed from the carbon and the positive part that is the hydrogen atom will be removed from carbon containing a minimum number of hydrogen atoms.
Complete solution:
As we already know that
So, we write the reaction as: -

Here we see that
Let us see which is the

So, the correct answer is Option A i.e.,
Additional information: Elimination reactions are commonly known by the kind of atoms or groups of atoms leaving the molecule. The removal of a hydrogen atom and a halogen atom is known as dehydrohalogenation. When both the leaving atoms are halogens then the reaction is known as dehalogenation. Similarly, the elimination of water molecules, usually from an alcohol, is known as dehydrogenation.
Note:Elimination reaction is an important method for the preparation of alkenes. Here Saytzeff product is the major product formed. According to Saytzeff rule, the negative part that is the halogen will be removed from the
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