Answer
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Hint: Steric effects are the nonbonding interactions which influence the conformation and reactivity of the ions and molecules in a chemical reaction. The products in the elimination reaction are influenced by the steric effect of the base considered in the reaction and form products accordingly.
Complete answer:
The product in the given reaction conditions follows Saytzeff’s rule and Hoffman rule. Saytzeff’s rule states that in an elimination reaction, the more substituted alkene is most favoured. But, steric interaction within the substrate prevents the formation of Saytzeff product and in that case, the formation of least substituted alkene takes place which is referred to as the Hoffman rule.
Now, as per question, the two bases considered in the reaction are $ NaOC{H_2}C{H_3} $ and $ KOC{(C{H_3})_3} $ . The ethoxide ion i.e., $ C{H_3}C{H_2}{O^ - } $ is small and sterically unhindered while the tertiary butoxide ion i.e., $ (C{H_3})C{O^ - } $ is bulky and sterically hindered.
Thus, in case of $ NaOC{H_2}C{H_3} $ , the product is formed as per Saytzeff’s rule and the reaction takes place as follows:
While in case of $ KOC{(C{H_3})_3} $ , the product is formed as per Hoffman’s rule and the reaction takes place as follows:
Hence, due to steric hindrance, $ NaOC{H_2}C{H_3} $ favours more substituted alkene whereas when $ KOC{(C{H_3})_3} $ is taken as base, then less substituted alkene predominates and the products formed in both the case are 1-methylcyclohex-1-ene and methylenecyclohexane respectively.
Note:
It is important to note that the elimination reactions are always regioselective, that means the products formed in the reaction are constitutional isomers to each other. During the reaction, the more stable product (either Saytzeff or Hoffman as per reaction conditions) is major while its less stable constitutional isomer is considered as a minor product.
Complete answer:
The product in the given reaction conditions follows Saytzeff’s rule and Hoffman rule. Saytzeff’s rule states that in an elimination reaction, the more substituted alkene is most favoured. But, steric interaction within the substrate prevents the formation of Saytzeff product and in that case, the formation of least substituted alkene takes place which is referred to as the Hoffman rule.
Now, as per question, the two bases considered in the reaction are $ NaOC{H_2}C{H_3} $ and $ KOC{(C{H_3})_3} $ . The ethoxide ion i.e., $ C{H_3}C{H_2}{O^ - } $ is small and sterically unhindered while the tertiary butoxide ion i.e., $ (C{H_3})C{O^ - } $ is bulky and sterically hindered.
Thus, in case of $ NaOC{H_2}C{H_3} $ , the product is formed as per Saytzeff’s rule and the reaction takes place as follows:
While in case of $ KOC{(C{H_3})_3} $ , the product is formed as per Hoffman’s rule and the reaction takes place as follows:
Hence, due to steric hindrance, $ NaOC{H_2}C{H_3} $ favours more substituted alkene whereas when $ KOC{(C{H_3})_3} $ is taken as base, then less substituted alkene predominates and the products formed in both the case are 1-methylcyclohex-1-ene and methylenecyclohexane respectively.
Note:
It is important to note that the elimination reactions are always regioselective, that means the products formed in the reaction are constitutional isomers to each other. During the reaction, the more stable product (either Saytzeff or Hoffman as per reaction conditions) is major while its less stable constitutional isomer is considered as a minor product.
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