Answer
Verified
401.1k+ views
Hint: In this question, 1- methylcyclohexene is an asymmetric alkene whereas HCl is a hydrogen halide. So, to solve this question we first need to know how the reaction between an asymmetric alkene and a hydrogen halide takes place.
Complete answer:
We know that hydrogen halides (HX) are protic acids. i.e., these acids produce protons as they ionize in solutions.
Now, when an asymmetric alkene reacts with a protic acid, the unsaturated carbon atom which has the most number of alkyl substituents will form a bond with the halide group whereas the unsaturated carbon atom which has the most number of hydrogen substituent will bind with the acidic hydrogen to form the major saturated product.
This phenomenon is known as Markovnikov's rule.
\[R-CH=C{{H}_{2}}+HX\to R-CH(X)-C{{H}_{3}}\text{ (major)}\]
So, according to this rule, the reaction between 1-methylcyclohexene and hydrochloric acid (HCl) will be as follows.
1-methylcyclohexene on treatment with HCl gas gives option (B) 1-chloro-1-methylcyclohexane
Additional information:
The speed of the reaction of the addition of hydrogen halide to alkene depends upon the hydrogen halide. The reaction rate increases as we go from HF to HI.
HF < HCl < HBr < HI
This is because, with the increase in the size of the halide atom, the bond strength of the hydrogen halide decreases, and the bonds break easily, which further helps in increasing the rate of the reaction.
Note:
It should be noted that when hydrogen bromide (HBr) is added to an asymmetrical alkene in the presence of an organic peroxide, the reaction follows the free radical mechanism, and the products are formed according to the anti-Markovnikov's rule which states that the protic acid is added to the more alkyl-substituted carbon atom.
Complete answer:
We know that hydrogen halides (HX) are protic acids. i.e., these acids produce protons as they ionize in solutions.
Now, when an asymmetric alkene reacts with a protic acid, the unsaturated carbon atom which has the most number of alkyl substituents will form a bond with the halide group whereas the unsaturated carbon atom which has the most number of hydrogen substituent will bind with the acidic hydrogen to form the major saturated product.
This phenomenon is known as Markovnikov's rule.
\[R-CH=C{{H}_{2}}+HX\to R-CH(X)-C{{H}_{3}}\text{ (major)}\]
So, according to this rule, the reaction between 1-methylcyclohexene and hydrochloric acid (HCl) will be as follows.
1-methylcyclohexene on treatment with HCl gas gives option (B) 1-chloro-1-methylcyclohexane
Additional information:
The speed of the reaction of the addition of hydrogen halide to alkene depends upon the hydrogen halide. The reaction rate increases as we go from HF to HI.
HF < HCl < HBr < HI
This is because, with the increase in the size of the halide atom, the bond strength of the hydrogen halide decreases, and the bonds break easily, which further helps in increasing the rate of the reaction.
Note:
It should be noted that when hydrogen bromide (HBr) is added to an asymmetrical alkene in the presence of an organic peroxide, the reaction follows the free radical mechanism, and the products are formed according to the anti-Markovnikov's rule which states that the protic acid is added to the more alkyl-substituted carbon atom.
Recently Updated Pages
Who among the following was the religious guru of class 7 social science CBSE
what is the correct chronological order of the following class 10 social science CBSE
Which of the following was not the actual cause for class 10 social science CBSE
Which of the following statements is not correct A class 10 social science CBSE
Which of the following leaders was not present in the class 10 social science CBSE
Garampani Sanctuary is located at A Diphu Assam B Gangtok class 10 social science CBSE
Trending doubts
A rainbow has circular shape because A The earth is class 11 physics CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Which are the Top 10 Largest Countries of the World?
How do you graph the function fx 4x class 9 maths CBSE
The Constitution of India was adopted on A 26 November class 10 social science CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
The Equation xxx + 2 is Satisfied when x is Equal to Class 10 Maths
Change the following sentences into negative and interrogative class 10 english CBSE