
A mixture of 1-chloropropane and 2-chloropropane when treated with alcoholic gives
A. prop ene
B. prop ene
C. a mixture of prop ene and prop ene
D. propanol
Answer
480.6k+ views
Hint: Alkyl halides when treated with alcoholic potassium hydroxide undergo dehydrohalogenation reaction to give alkenes as the product. The alkene is formed by the removal of the hydrogen atom present in the atom, along with the removal of chlorine. In other words, the product is an alkene with an double bond.
Complete step by step solution:
Alkyl halides tend to form the more substituted alkenes when treated with alcoholic . In this reaction, first, the alcohol and the potassium hydroxide split up into their respective ions:
The potassium ion and the ethoxy ion then combines to form potassium ethoxide:
Potassium ethoxide so formed is a very strong base, and like all bases, it tends to attract hydrogen atoms. Thus, this molecule abstracts the atom (hydrogen atom present on the carbon atom next to the carbon atom holding the chlorine atom) from both the chloropropane and chloropropane. The chlorine atom then leaves with the hydrogen, and a double bond is formed between the carbon atom which has the chlorine atom, and the carbon atom next to it, thus forming the alkene.
Let us see the exact mechanism of this for chloropropane and chloropropane:
For chloropropane, the reaction is as follows:
Thus, the product formed is prop- -ene.
For chloropropane, the reaction is as follows:
Even in the case of chloropropane, the same product is being formed. This is because as the propane molecule has just three carbon atoms, the carbon atoms on either ends of the molecule are both equally preferred atoms, and thus, the product formed will be the same since the double bond can only be formed between the central carbon atom and a carbon atom at either end.
Thus, the products of dehydrohalogenation of chloropropane and chloropropane are the same, and we get prop ene as the product.
Hence the option ‘A’ is the correct solution for the given question.
Note:
Since the propane molecule is a symmetrical molecule, it is impossible to have a product named prop ene, as IUPAC nomenclature names double bonds according to the first carbon atom in which they are present. Note that the atom is abstracted as it is the most acidic hydrogen in the compound, due to the high electronegativity of the halogen.
Complete step by step solution:
Alkyl halides tend to form the more substituted alkenes when treated with alcoholic
The potassium ion and the ethoxy ion then combines to form potassium ethoxide:
Potassium ethoxide so formed is a very strong base, and like all bases, it tends to attract hydrogen atoms. Thus, this molecule abstracts the
Let us see the exact mechanism of this for
For
Thus, the product formed is prop-
For

Even in the case of
Thus, the products of dehydrohalogenation of
Hence the option ‘A’ is the correct solution for the given question.
Note:
Since the propane molecule is a symmetrical molecule, it is impossible to have a product named prop
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