Answer
382.2k+ views
Hint: Hydrolysis is the process of simple reaction of the addition of water to a substance. Base hydrolysis of an ester with a strong base yields a carboxylate salt and alcohol. Kolbe’s electrolysis gives the decarboxylated product which is an alkane along with the production of carbon dioxide by a free radical mechanism.
Complete step by step answer:
We know that Kolbe’s electrolysis of a molecule gives the dimer products by combining free radicals after decarboxylation to form alkane. So we have been given ethane through Kolbe’s electrolysis which means that we have the alkyl group as methyl group in a carboxylic acid.
Further, as only methyl groups are present in carboxylic acid so the carboxylic acid here would be ethanoic acid. Now the carboxylic acid is ethanoic acid then the ester will be formed by removing the hydrogen in ethanoic acid, that is $C{H_3}COOC{H_3}$ according to the given conditions. The ester name is methyl ethanoate.
The reaction involved in the following processes are as follows
$C{H_3}COOC{H_3} + NaOH \to C{H_3}COONa + C{H_3}OH$. Now this sodium salt of ethanoic acid undergoes Kolbe’s electrolysis to form methyl radical which dimerises to form alkane. The reaction involved is given below
$C{H_3}CO{O^ - } \to C{H_3}CO{O^ \bullet }$
$C{H_3}CO{O^ \bullet } \to C{H_3}^ \bullet + C{O_2}$
$2C{H_3}^ \bullet \to C{H_3} - C{H_3}$
Therefore from the above reaction, we infer that the required ester is methyl ethanoate.
Hence the correct answer is option B.
Note:
Esters can be cleaved back into a carboxylic acid and alcohol by reaction with water and base. This reaction is called a saponification reaction which is a characteristic reaction of esters. Also as basic conditions are there, a carboxylate ion is made rather than a carboxylic acid.
Complete step by step answer:
We know that Kolbe’s electrolysis of a molecule gives the dimer products by combining free radicals after decarboxylation to form alkane. So we have been given ethane through Kolbe’s electrolysis which means that we have the alkyl group as methyl group in a carboxylic acid.
Further, as only methyl groups are present in carboxylic acid so the carboxylic acid here would be ethanoic acid. Now the carboxylic acid is ethanoic acid then the ester will be formed by removing the hydrogen in ethanoic acid, that is $C{H_3}COOC{H_3}$ according to the given conditions. The ester name is methyl ethanoate.
The reaction involved in the following processes are as follows
$C{H_3}COOC{H_3} + NaOH \to C{H_3}COONa + C{H_3}OH$. Now this sodium salt of ethanoic acid undergoes Kolbe’s electrolysis to form methyl radical which dimerises to form alkane. The reaction involved is given below
$C{H_3}CO{O^ - } \to C{H_3}CO{O^ \bullet }$
$C{H_3}CO{O^ \bullet } \to C{H_3}^ \bullet + C{O_2}$
$2C{H_3}^ \bullet \to C{H_3} - C{H_3}$
Therefore from the above reaction, we infer that the required ester is methyl ethanoate.
Hence the correct answer is option B.
Note:
Esters can be cleaved back into a carboxylic acid and alcohol by reaction with water and base. This reaction is called a saponification reaction which is a characteristic reaction of esters. Also as basic conditions are there, a carboxylate ion is made rather than a carboxylic acid.
Recently Updated Pages
In a flask the weight ratio of CH4g and SO2g at 298 class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
In a flask colourless N2O4 is in equilibrium with brown class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
In a first order reaction the concentration of the class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
In a first order reaction the concentration of the class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
In a fermentation tank molasses solution is mixed with class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
In a face centred cubic unit cell what is the volume class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Trending doubts
Which are the Top 10 Largest Countries of the World?
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference Between Plant Cell and Animal Cell
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Give 10 examples for herbs , shrubs , climbers , creepers
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Change the following sentences into negative and interrogative class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Write a letter to the principal requesting him to grant class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Name 10 Living and Non living things class 9 biology CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Black foot disease is caused by the pollution of groundwater class 12 biology CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)