Answer
Verified
416.7k+ views
Hint: Aniline cannot be directly converted to nitrobenzene directly. It needs to be converted to a diazonium salt first which can then be treated with other chemical agents to form the nitrobenzene.
Complete Stepwise Solution:
Aniline is a basic molecule which comprises an amino group attached to the benzene ring. This can be treated with a cold dilute acidic solution sodium nitrite in the temperature range of $ {\left( {{\text{0 - 5}}} \right)^{{\text{ 0}}}}{\text{C}} $ to form diazo compounds which form the intermediate for the transformation reaction. This is then treated with hydrogen fluoroborate or $ {\text{HB}}{{\text{F}}_{\text{4}}} $ to form the fluro salt of the diazo compound. Then this salt is treated with copper and sodium nitrite to form nitrobenzene. The reaction can be written as follows:
Alternatively, there is one more route for the preparation of nitrobenzene from aniline. aniline can be treated with a cold dilute acidic solution sodium nitrite in the temperature range of $ {\left( {{\text{0 - 5}}} \right)^{{\text{ 0}}}}{\text{C}} $ to form diazo compound. Then diazonium chloride is then hydrolysed in presence of hypophosphorous acid and water to form benzene. The benzene is then treated with concentrated solution of sulphuric acid and nitric acid to form the nitrobenzene. The reaction can be written as follows:
Note:
The reaction of Aniline with the cold dilute acidic solution of sodium nitrate to form the diazonium salt serves to be an intermediate for the preparation of a number of compounds. The diazo salt is not stable at high temperatures and hence the reaction takes place at cold temperature conditions.
Complete Stepwise Solution:
Aniline is a basic molecule which comprises an amino group attached to the benzene ring. This can be treated with a cold dilute acidic solution sodium nitrite in the temperature range of $ {\left( {{\text{0 - 5}}} \right)^{{\text{ 0}}}}{\text{C}} $ to form diazo compounds which form the intermediate for the transformation reaction. This is then treated with hydrogen fluoroborate or $ {\text{HB}}{{\text{F}}_{\text{4}}} $ to form the fluro salt of the diazo compound. Then this salt is treated with copper and sodium nitrite to form nitrobenzene. The reaction can be written as follows:
Alternatively, there is one more route for the preparation of nitrobenzene from aniline. aniline can be treated with a cold dilute acidic solution sodium nitrite in the temperature range of $ {\left( {{\text{0 - 5}}} \right)^{{\text{ 0}}}}{\text{C}} $ to form diazo compound. Then diazonium chloride is then hydrolysed in presence of hypophosphorous acid and water to form benzene. The benzene is then treated with concentrated solution of sulphuric acid and nitric acid to form the nitrobenzene. The reaction can be written as follows:
Note:
The reaction of Aniline with the cold dilute acidic solution of sodium nitrate to form the diazonium salt serves to be an intermediate for the preparation of a number of compounds. The diazo salt is not stable at high temperatures and hence the reaction takes place at cold temperature conditions.
Recently Updated Pages
Who among the following was the religious guru of class 7 social science CBSE
what is the correct chronological order of the following class 10 social science CBSE
Which of the following was not the actual cause for class 10 social science CBSE
Which of the following statements is not correct A class 10 social science CBSE
Which of the following leaders was not present in the class 10 social science CBSE
Garampani Sanctuary is located at A Diphu Assam B Gangtok class 10 social science CBSE
Trending doubts
Which are the Top 10 Largest Countries of the World?
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
How do you graph the function fx 4x class 9 maths CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
Change the following sentences into negative and interrogative class 10 english CBSE
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
The Equation xxx + 2 is Satisfied when x is Equal to Class 10 Maths
Write a letter to the principal requesting him to grant class 10 english CBSE
What organs are located on the left side of your body class 11 biology CBSE