Answer
Verified
390.9k+ views
Hint :Here we have two questions. We know that Cumene is an organic compound acquired by Friedel-Crafts alkylation of benzene with propylene. That is, Cumene means isopropyl benzene. On oxidation of cumene and on further action we will get phenol. We can distinguish between phenol and ethanol by reaction with neutral $ FeC{l_3} $ .
Complete step by step solution:
Now conversion of cumene to phenol,
On oxidation of cumene (Isopropyl benzene) in the presence of air, cumene hydroperoxide is found. Upon further action of cumene hydroperoxide with dilute acid, phenols are produced.
Acetone is also made as one of the by-products of the reaction in large quantities. Therefore, phenols prepared by these techniques need purifications.
Now distinguish between phenol and ethanol by reaction with neutral $ FeC{l_3} $ .
Phenol reacts with aqueous neutral $ FeC{l_3} $ to form ferric phenoxide complex, which is violet coloured. But ethanol (alcohol) does not respond to $ FeC{l_3} $ .
Note:
We can prepare phenols from haloarenes or from benzene sulphonic acid or from diazonium salts and by many other methods. We can also distinguish phenol and ethanol by haloform test. Ethanol when treated with an iodine, iodoform is obtained which is yellow needle shaped. But phenol does not show haloform test.
$ C{H_3}C{H_2}OH\xrightarrow{{{I_2} + O{H^ - }}}CH{I_3} $ .
Phenol is weakly acidic hence turns blue litmus red. It gives a positive dye test, whereas alcohols (ethanol) do not show dye test.
Complete step by step solution:
Now conversion of cumene to phenol,
On oxidation of cumene (Isopropyl benzene) in the presence of air, cumene hydroperoxide is found. Upon further action of cumene hydroperoxide with dilute acid, phenols are produced.
Acetone is also made as one of the by-products of the reaction in large quantities. Therefore, phenols prepared by these techniques need purifications.
Now distinguish between phenol and ethanol by reaction with neutral $ FeC{l_3} $ .
Phenol reacts with aqueous neutral $ FeC{l_3} $ to form ferric phenoxide complex, which is violet coloured. But ethanol (alcohol) does not respond to $ FeC{l_3} $ .
Note:
We can prepare phenols from haloarenes or from benzene sulphonic acid or from diazonium salts and by many other methods. We can also distinguish phenol and ethanol by haloform test. Ethanol when treated with an iodine, iodoform is obtained which is yellow needle shaped. But phenol does not show haloform test.
$ C{H_3}C{H_2}OH\xrightarrow{{{I_2} + O{H^ - }}}CH{I_3} $ .
Phenol is weakly acidic hence turns blue litmus red. It gives a positive dye test, whereas alcohols (ethanol) do not show dye test.
Recently Updated Pages
How many sigma and pi bonds are present in HCequiv class 11 chemistry CBSE
Mark and label the given geoinformation on the outline class 11 social science CBSE
When people say No pun intended what does that mea class 8 english CBSE
Name the states which share their boundary with Indias class 9 social science CBSE
Give an account of the Northern Plains of India class 9 social science CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
Trending doubts
Difference Between Plant Cell and Animal Cell
Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
10 examples of evaporation in daily life with explanations
Write a letter to the principal requesting him to grant class 10 english CBSE
The Equation xxx + 2 is Satisfied when x is Equal to Class 10 Maths
Name 10 Living and Non living things class 9 biology CBSE