
Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions difficulty?
Answer
434.5k+ views
6 likes
Hint:
Electrophilic substitution reactions are chemical reactions in which an electrophile displaces a group in a compound, typically but not always hydrogen.
Nucleophilic substitution reactions are those reactions in which substitution is brought about by a nucleophile. These reactions are denoted by { S }_{ N } (S stands for substitution and N for nucleophile). One of the most common examples of this type of reaction is the hydrolysis of an alkyl halide by aqueous to give alcohols.
Complete step-by-step answer:
Benzene is a planar molecule having delocalized electrons above and below the plane of the ring. Hence, it is electron-rich. As a result, it is highly attractive to electron-deficient species i.e., electrophiles. Therefore, it undergoes electrophilic substitution reactions very easily.
Nucleophiles are electron-rich. Due to the presence of an electron cloud of delocalized electrons on the benzene ring nucleophilic attack is difficult. Hence, they are repelled by benzene. Hence, benzene undergoes nucleophilic substitutions with difficulty.
Additional Information:
Electrophilic substitution reactions are chemical reactions in which an electrophile displaces a functional group in a compound, which is typically, but not always, a hydrogen atom.
Electrophilic aromatic substitution reactions are characteristic of aromatic compounds and are important ways of introducing functional groups onto benzene rings.
Note:
The possibility to make a mistake is that nucleophilic reactions also occur in benzene when a Lewis acid like { AlCl }_{ 3 } binds the halogen which creates a positive charge in the alkyl group. But the fact is Electrophilic substitutions are preferred over nucleophilic substitution reactions.
Electrophilic substitution reactions are chemical reactions in which an electrophile displaces a group in a compound, typically but not always hydrogen.
Nucleophilic substitution reactions are those reactions in which substitution is brought about by a nucleophile. These reactions are denoted by { S }_{ N } (S stands for substitution and N for nucleophile). One of the most common examples of this type of reaction is the hydrolysis of an alkyl halide by aqueous to give alcohols.
Complete step-by-step answer:
Benzene is a planar molecule having delocalized electrons above and below the plane of the ring. Hence, it is electron-rich. As a result, it is highly attractive to electron-deficient species i.e., electrophiles. Therefore, it undergoes electrophilic substitution reactions very easily.
Nucleophiles are electron-rich. Due to the presence of an electron cloud of delocalized electrons on the benzene ring nucleophilic attack is difficult. Hence, they are repelled by benzene. Hence, benzene undergoes nucleophilic substitutions with difficulty.

Additional Information:
Electrophilic substitution reactions are chemical reactions in which an electrophile displaces a functional group in a compound, which is typically, but not always, a hydrogen atom.
Electrophilic aromatic substitution reactions are characteristic of aromatic compounds and are important ways of introducing functional groups onto benzene rings.
Note:
The possibility to make a mistake is that nucleophilic reactions also occur in benzene when a Lewis acid like { AlCl }_{ 3 } binds the halogen which creates a positive charge in the alkyl group. But the fact is Electrophilic substitutions are preferred over nucleophilic substitution reactions.
Recently Updated Pages
Master Class 12 Business Studies: Engaging Questions & Answers for Success

Master Class 12 English: Engaging Questions & Answers for Success

Master Class 12 Social Science: Engaging Questions & Answers for Success

Master Class 12 Chemistry: Engaging Questions & Answers for Success

Class 12 Question and Answer - Your Ultimate Solutions Guide

Master Class 11 Economics: Engaging Questions & Answers for Success

Trending doubts
Draw a labelled sketch of the human eye class 12 physics CBSE

a Tabulate the differences in the characteristics of class 12 chemistry CBSE

Which one of the following is a true fish A Jellyfish class 12 biology CBSE

Why is the cell called the structural and functional class 12 biology CBSE

Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE

Write the difference between solid liquid and gas class 12 chemistry CBSE
