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Hint: In electrophilic aromatic substitution reaction, the benzene ring acts as a nucleophile. It donates a pair of pi electrons to suitable electrophile. In the next step, deprotonation occurs.
Complete Step by step answer: Explain the mechanism for nitration of benzene.
Benzene reacts with nitric acid and sulphuric acid to form nitrobenzene. It is an example of electrophilic aromatic substitution reaction. One hydrogen atom of benzene ring is replaced with nitro group. Nitric acid reacts with sulphuric acid to form nitronium ions.
The pi electrons of benzene are donated to nitronium ions. A carbon-nitrogen bond is formed and the neighboring carbon atom gains unit positive charge. In this step, the aromaticity of the ring is broken. In the next step, this intermediate loses a proton to the water molecule. In this step, the aromaticity of the ring is regenerated.
Additional information: Some other examples of electrophilic aromatic substitution reaction include sulphation, Friedel craft alkylation and Friedel craft acylation reactions.
Note: Aromatic compounds do not undergo addition reactions. Instead they undergo substitution reactions. If an additional reaction is carried out for the aromatic compounds, then the aromaticity of the benzene ring will be lost. This will decrease the stability. However, for substitution reactions, the aromaticity of benzene rings is restored. Hence, substitution is preferred over addition for aromatic compounds.
Complete Step by step answer: Explain the mechanism for nitration of benzene.
Benzene reacts with nitric acid and sulphuric acid to form nitrobenzene. It is an example of electrophilic aromatic substitution reaction. One hydrogen atom of benzene ring is replaced with nitro group. Nitric acid reacts with sulphuric acid to form nitronium ions.
The pi electrons of benzene are donated to nitronium ions. A carbon-nitrogen bond is formed and the neighboring carbon atom gains unit positive charge. In this step, the aromaticity of the ring is broken. In the next step, this intermediate loses a proton to the water molecule. In this step, the aromaticity of the ring is regenerated.
Additional information: Some other examples of electrophilic aromatic substitution reaction include sulphation, Friedel craft alkylation and Friedel craft acylation reactions.
Note: Aromatic compounds do not undergo addition reactions. Instead they undergo substitution reactions. If an additional reaction is carried out for the aromatic compounds, then the aromaticity of the benzene ring will be lost. This will decrease the stability. However, for substitution reactions, the aromaticity of benzene rings is restored. Hence, substitution is preferred over addition for aromatic compounds.
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