
For the reaction: total pressure , degree of dissociation . Then would be:
A.
B.
C.
D.
Answer
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Hint: is equilibrium constant for the gaseous mixture. It is used when the concentration of gases at equilibrium is expressed in atmospheric pressure. The degree of dissociation is the fraction of reactant that is dissociated.
Complete step by step answer:
The equilibrium in the given reaction is homogeneous equilibrium since all the components are in the gaseous phase.
Now in the reaction,
Let moles be taken of in a closed vessel. Once equilibrium is reached moles of dissociate into . One mole of gives one mole of each . Thus moles of gives moles of and moles of .
Remember when , becomes a degree of dissociation .
So,
It is given that degree of dissociation is . it means that .
So total moles at equilibrium
Now in case of gaseous reactants and products for calculating we consider partial pressure of gaseous reactants and products.
Partial pressure of any gas is equal to the product of total pressure and mole fraction of that gas.
In our example, the total pressure is and we know the number of moles of each component.
So, partial pressure of can be given as-
Partial pressure of -
Partial pressure of -
Now, we need to calculate in terms of partial pressure of reactants and products-
So
So, the correct answer is Option C.
Note: is calculated when the reactants and products are in gaseous phase and the concentrations are expressed in terms of partial pressure . is the equilibrium constant of the reaction when the concentrations of reactants and products at equilibrium are expressed in molarity. is related to by the equation- where is the difference between the number of moles of gaseous products and reactants, is gas constant and is the temperature.
Complete step by step answer:
The equilibrium in the given reaction is homogeneous equilibrium since all the components are in the gaseous phase.
Now in the reaction,
Let
Remember when
So,
Initial moles: | |||
At equilibrium: |
It is given that degree of dissociation is
So total moles at equilibrium
Now in case of gaseous reactants and products for calculating
Partial pressure of any gas is equal to the product of total pressure and mole fraction of that gas.
In our example, the total pressure is
So, partial pressure of
Partial pressure of
Partial pressure of
Now, we need to calculate
So
So, the correct answer is Option C.
Note:
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