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Hint: Geminal dihalide hydrolysis is an organic reaction in which the gem-halide reacts with water or undergo hydrolysis in an alkaline medium. There are two products which can be formed.
Complete step by step solution: Geminal dihalides are dihalogen compounds in which both the halogen atoms are attached to the same carbon atom.
For example, Ethylidene dichloride
Suppose, there is a geminal dihalide \[C{{H}_{3}}CH{{(Cl)}_{2}}\] is present, the hydrolysis of gem-halides takes place in alkaline medium. So, we will hydrolyse it in the presence of aqueous NaOH/KOH.
On hydrolysis, both of the chlorine group will be replaced by hydroxyl group (OH),
\[C{{H}_{3}}CH{{(OH)}_{2}}\] will be formed.
As both the hydroxyl groups are present on the same carbon, this compound is not stable. So, water acts as a leaving group i.e. \[{{H}_{2}}O\] will be removed.
Thus, forming an aldehyde group \[C{{H}_{3}}CHO\], this compound is called acetaldehyde. But this is the case when gem-dihalide is present at the terminal position.
\[C{{H}_{3}}CH{{(Cl)}_{2}}\xrightarrow[aq]{KOH}C{{H}_{3}}CH{{(OH)}_{2}}\to C{{H}_{3}}COH+{{H}_{2}}O\]
Now, let's take a compound \[C{{H}_{3}}C{{(Cl)}_{2}}C{{H}_{3}}\], on hydrolysis the chlorine groups will be replaced by hydroxyl groups, \[C{{H}_{3}}C{{(OH)}_{2}}C{{H}_{3}}\]will be obtained.
Similarly, as the previous example, this compound will also be unstable, thus water will act as a leaving group.
Thus, forming a keto or carbonyl group \[C{{H}_{3}}COC{{H}_{3}}\], this compound is called acetone.
\[C{{H}_{3}}C{{(Cl)}_{2}}C{{H}_{3}}\xrightarrow[aq]{KOH}C{{H}_{3}}COC{{H}_{3}}+2KCl+{{H}_{2}}O\]
Therefore, from the above statements we can conclude that the correct option is (c).
Note: Geminal dihalides are prepared by reacting a non-enolizable aldehyde and/or ketone with phosgene or thionyl chloride in the presence of an organic-phosphorus compound.
Complete step by step solution: Geminal dihalides are dihalogen compounds in which both the halogen atoms are attached to the same carbon atom.
For example, Ethylidene dichloride
Suppose, there is a geminal dihalide \[C{{H}_{3}}CH{{(Cl)}_{2}}\] is present, the hydrolysis of gem-halides takes place in alkaline medium. So, we will hydrolyse it in the presence of aqueous NaOH/KOH.
On hydrolysis, both of the chlorine group will be replaced by hydroxyl group (OH),
\[C{{H}_{3}}CH{{(OH)}_{2}}\] will be formed.
As both the hydroxyl groups are present on the same carbon, this compound is not stable. So, water acts as a leaving group i.e. \[{{H}_{2}}O\] will be removed.
Thus, forming an aldehyde group \[C{{H}_{3}}CHO\], this compound is called acetaldehyde. But this is the case when gem-dihalide is present at the terminal position.
\[C{{H}_{3}}CH{{(Cl)}_{2}}\xrightarrow[aq]{KOH}C{{H}_{3}}CH{{(OH)}_{2}}\to C{{H}_{3}}COH+{{H}_{2}}O\]
Now, let's take a compound \[C{{H}_{3}}C{{(Cl)}_{2}}C{{H}_{3}}\], on hydrolysis the chlorine groups will be replaced by hydroxyl groups, \[C{{H}_{3}}C{{(OH)}_{2}}C{{H}_{3}}\]will be obtained.
Similarly, as the previous example, this compound will also be unstable, thus water will act as a leaving group.
Thus, forming a keto or carbonyl group \[C{{H}_{3}}COC{{H}_{3}}\], this compound is called acetone.
\[C{{H}_{3}}C{{(Cl)}_{2}}C{{H}_{3}}\xrightarrow[aq]{KOH}C{{H}_{3}}COC{{H}_{3}}+2KCl+{{H}_{2}}O\]
Therefore, from the above statements we can conclude that the correct option is (c).
Note: Geminal dihalides are prepared by reacting a non-enolizable aldehyde and/or ketone with phosgene or thionyl chloride in the presence of an organic-phosphorus compound.
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