
Give the diazotization reaction of aniline. Also, give the chemical reaction involved in the preparation of red azo dye and light yellow azo dye.
Answer
495k+ views
1 likes
Hint: The conversion of a primary amine into its diazonium salt is called diazotization. The temperature required for this reaction is in the range of 273K to 278K.
Complete step by step answer: Aromatic diazonium salt is generally prepared by adding a cold aqueous solution of sodium nitrite to the solution or suspension of a primary aromatic amine in acid at 273K to 278K. The general reaction is written as:
Where Ar is an aryl group and X is halogen.
In the case of aniline diazotization reaction is written as:
Arenediazonium salts react with a highly reactive aromatic compound such as phenol and amines to form brightly colored azo compounds. This reaction is known as a coupling reaction.
The chemical reaction involved in the preparation of red azo dye:
In this reaction, diazonium salt reacts with β-Naphthol in the presence of dil. NaOH at PH 9-10, i.e. in alkali medium to give β-Naphthol aniline dye, i.e. red azo dye.
The chemical reaction involved in the formation of yellow dye:
In this reaction, diazonium salt reacts with aniline in the presence of dil. NaOH at PH 4-5, i.e. in acidic medium to give p-Aminoazobenzene, i.e. yellow dye.
Note: The well-known indicator methyl orange used in acid-base titration is also prepared by a coupling reaction. So we can say diazonium salts are very good intermediates.
Complete step by step answer: Aromatic diazonium salt is generally prepared by adding a cold aqueous solution of sodium nitrite to the solution or suspension of a primary aromatic amine in acid at 273K to 278K. The general reaction is written as:
Where Ar is an aryl group and X is halogen.
In the case of aniline diazotization reaction is written as:

Arenediazonium salts react with a highly reactive aromatic compound such as phenol and amines to form brightly colored azo compounds. This reaction is known as a coupling reaction.
The chemical reaction involved in the preparation of red azo dye:

In this reaction, diazonium salt reacts with β-Naphthol in the presence of dil. NaOH at PH 9-10, i.e. in alkali medium to give β-Naphthol aniline dye, i.e. red azo dye.
The chemical reaction involved in the formation of yellow dye:

In this reaction, diazonium salt reacts with aniline in the presence of dil. NaOH at PH 4-5, i.e. in acidic medium to give p-Aminoazobenzene, i.e. yellow dye.
Note: The well-known indicator methyl orange used in acid-base titration is also prepared by a coupling reaction. So we can say diazonium salts are very good intermediates.
Latest Vedantu courses for you
Grade 11 Science PCM | CBSE | SCHOOL | English
CBSE (2025-26)
School Full course for CBSE students
₹41,848 per year
Recently Updated Pages
Write all the integers between the given pairs write class 7 maths CBSE

Fill in the blank with a relative pronoun The earthquake class 7 english CBSE

Employees join unions to fulfil their needs A Social class 7 social science CBSE

The difference between the place value of two servers class 7 maths CBSE

How do you find the percent increase from 18 to 26 class 7 maths CBSE

Who became the ruler of the Marathas after Shivaji class 7 social science CBSE

Trending doubts
Give 10 examples of unisexual and bisexual flowers

Draw a labelled sketch of the human eye class 12 physics CBSE

Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE

Differentiate between insitu conservation and exsitu class 12 biology CBSE

What are the major means of transport Explain each class 12 social science CBSE

Draw a diagram of a flower and name the parts class 12 biology ICSE
