
Glucose on reaction with acetic acid gives glucose Penta acetate. What does it suggest about the structure of glucose?
Answer
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Hint: Recall the reaction of glucose with acetic anhydride. It is the same reaction. Glucose with acetic anhydride also gives glucose Penta acetate. The reaction is known as the acetylation of glucose. The glucose Penta acetate is a very stable compound.
Complete Step By Step Answer:
The above question states that “Glucose on reaction with acetic acid gives glucose Penta acetate”. Now we will have to look into the reaction of glucose with Penta acetate to solve the problem and to find out the structure of glucose.
When glucose reacts with acetic acid it gives Penta acetate. The reaction takes place under the presence of Zinc chloride. The reaction is as follows:
In the above reaction, we can see that the glucose structure has OH groups in it. When these OH groups react with acetic acid the OH groups of glucose get replaced by the acetate group. Thus, we can say that the reaction shows the presence of OH groups in the structure of the glucose.
This glucose Penta acetate is the beta-D form of glucose. It is insoluble in water. It is soluble in chloroform and methanol. Its chemical stability is very high and has a long shelf life.
Note:
The above reaction is similar to that of the reaction of glucose with acetic anhydride. This is also produced by glucose Penta acetate and confirms the presence of OH groups in glucose. This reaction is known as an acetylation reaction. The glucose Penta acetate is the protected form of glucose that is a key building block of any chemical synthesis of glucose-containing oligosaccharides or glycoconjugates.
Complete Step By Step Answer:
The above question states that “Glucose on reaction with acetic acid gives glucose Penta acetate”. Now we will have to look into the reaction of glucose with Penta acetate to solve the problem and to find out the structure of glucose.
When glucose reacts with acetic acid it gives Penta acetate. The reaction takes place under the presence of Zinc chloride. The reaction is as follows:

In the above reaction, we can see that the glucose structure has
This glucose Penta acetate is the beta-D form of glucose. It is insoluble in water. It is soluble in chloroform and methanol. Its chemical stability is very high and has a long shelf life.
Note:
The above reaction is similar to that of the reaction of glucose with acetic anhydride. This is also produced by glucose Penta acetate and confirms the presence of
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