
A and B are respectively
(a)
,
(b)
,
(c) ,
(d)
,







Answer
502.5k+ views
Hint: Glycerol has 3 alkyl groups each attached with an OH group to it. The hydroxyl groups can be easily removed to form a tautomerism product.
Complete step by step solution:
has a dehydrating property. It abstracts water molecules from glycerol and also oxidises it to unsaturated aldehyde or acrylic aldehyde or acrolein( a tautomerism product). In the presence of HOCl the double bond shifts to the middle carbon and forms a carbanion and a carbocation. of HOCl forms a bond with the carbocation and attacks the carbanion giving us the final product.
The mechanism of the reaction is shown as
So, the correct answer is “Option B”.
Additional Information:
-Carbocation is a species in which the carbon atom has a positive charge on it and three bonds. These are basically carbon cations. These are very reactive species and are unstable. Their instability is due to the incomplete octet. Carbanions are carbon with negative charge. It is also trivalent. Like carbocation these are also highly unstable.
-Acrolein formed is a dehydrated product of glycerol when it is reacted with . It is a colourless liquid with an acrid smell. This actually formed by the tautomerization of glycerol. Tautomers are structural isomers in which the chemical compound can readily convert. Tautomerism is mainly shown by nucleic acids and amino acids. There are chances that it is confused with resonance structures. But both are different. Tautomers can be distinguished by spectral data. Resonance structures cannot be distinguished by spectral data. One of the examples is keto-enol tautomerism. Another name for tautomerism is thigmotropism.
Note: Water molecule is abstracted by to give acrylic aldehyde. This then reacts with HOCl to give a substituted product. Which should note that the double bond of the unsaturated aldehyde is shifted to the middle carbon and the attacks this carbanion. attacks the carbocation formed.
Complete step by step solution:
The mechanism of the reaction is shown as

So, the correct answer is “Option B”.
Additional Information:
-Carbocation is a species in which the carbon atom has a positive charge on it and three bonds. These are basically carbon cations. These are very reactive species and are unstable. Their instability is due to the incomplete octet. Carbanions are carbon with negative charge. It is also trivalent. Like carbocation these are also highly unstable.
-Acrolein formed is a dehydrated product of glycerol when it is reacted with
Note: Water molecule is abstracted by
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