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Hint: To solve this we must know that hydrazobenzene is also known as diphenylhydrazine. The structure is two benzene rings to which $ - {\text{NH}}$ groups are attached. These two rings are then connected through the nitrogen-nitrogen $\left( {{\text{N}} - {\text{N}}} \right)$ bond. ${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$ which is known as sulphuric acid creates an acidic medium. A rearrangement reaction occurs.
Complete solution:
We know that hydrazobenzene as the name suggests hydrazo group is $ - {\text{NH}}$ group and benzene indicates that this hydrazo group is attached to the benzene ring.
Hydrazobenzene is two benzene rings to which $ - {\text{NH}}$ groups are attached. These two rings are then connected through the nitrogen-nitrogen $\left( {{\text{N}} - {\text{N}}} \right)$ bond.
The structure for hydrazobenzene is as follows:
${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$ which is known as sulphuric acid creates an acidic medium. Hydrazobenzene in an acidic medium accepts protons from the sulphuric acid. In an acidic medium, hydrazobenzene undergoes a rearrangement reaction.
The mechanism of the reaction when hydrazobenzene reacts with sulphuric acid i.e. ${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$ is as follows:
In the reaction, where hydrazobenzene reacts with sulphuric acid i.e. ${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$ a rearrangement reaction leads to the formation of benzidine. Thus, benzidine is a product of rearrangement of hydrazobenzene in an acidic medium.
Benzidine is not a naturally occurring substance and is synthesized mainly from hydrazobenzene on reacting it with sulphuric acid i.e. ${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$.
Thus, hydrazobenzene on treatment with ${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$ forms benzidine.
Thus, the correct option is (C) benzidine.
Note: Benzidine is greyish-red, yellowish or white coloured powder. Benzidine can also be synthesized from nitrobenzene. Nitrobenzene is first converted to diphenylhydrazine or hydrazobenzene using iron powder as a reducing agent which then undergoes the same rearrangement reaction in acidic medium as shown above.
Complete solution:
We know that hydrazobenzene as the name suggests hydrazo group is $ - {\text{NH}}$ group and benzene indicates that this hydrazo group is attached to the benzene ring.
Hydrazobenzene is two benzene rings to which $ - {\text{NH}}$ groups are attached. These two rings are then connected through the nitrogen-nitrogen $\left( {{\text{N}} - {\text{N}}} \right)$ bond.
The structure for hydrazobenzene is as follows:
${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$ which is known as sulphuric acid creates an acidic medium. Hydrazobenzene in an acidic medium accepts protons from the sulphuric acid. In an acidic medium, hydrazobenzene undergoes a rearrangement reaction.
The mechanism of the reaction when hydrazobenzene reacts with sulphuric acid i.e. ${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$ is as follows:
In the reaction, where hydrazobenzene reacts with sulphuric acid i.e. ${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$ a rearrangement reaction leads to the formation of benzidine. Thus, benzidine is a product of rearrangement of hydrazobenzene in an acidic medium.
Benzidine is not a naturally occurring substance and is synthesized mainly from hydrazobenzene on reacting it with sulphuric acid i.e. ${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$.
Thus, hydrazobenzene on treatment with ${{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}$ forms benzidine.
Thus, the correct option is (C) benzidine.
Note: Benzidine is greyish-red, yellowish or white coloured powder. Benzidine can also be synthesized from nitrobenzene. Nitrobenzene is first converted to diphenylhydrazine or hydrazobenzene using iron powder as a reducing agent which then undergoes the same rearrangement reaction in acidic medium as shown above.
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