Answer
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Hint: The reaction involves the electrophilic substitution reaction and also the substituent attached to the benzene ring plays an important role in deciding the position of the electrophile to replace the hydrogen in the benzene ring.
Complete step by step solution:
It is given that the concentrated nitric acid and sulphuric acid reacts with the nitrobenzene leading to addition of another nitro group by replacement of hydrogen in the benzene ring. This is known as the nitration process. It takes place as follows:
- Firstly the $HN{{O}_{3}}\,and\,{{H}_{2}}S{{O}_{4}}$, react to form the electrophile, as the nitric acid gains proton from sulphuric acid, followed by losing a water molecule and forming the nitronium ion.
- In the nitrobenzene compound, the nitro- group is an electron-withdrawing group which deactivates the ortho- and the para- position for the electrophilic substitution by decreasing the electron density at these position as can be seen in its resonating structures.
This leads to the meta-position being most electron-dense, the favourable position for the electrophile to attach.
- So, when the nitronium ion electrophile attacks the benzene ring of the nitrobenzene compound, to forming the intermediate carbocation, which loses its proton to the Lewis base of $HS{{O}_{4}}^{-}$. Thus, forming a meta-substituted dinitrobenzene compound.
Therefore, the nitration of Nitrobenzene compound forms option (B) 1,3- Dinitrobenzene as the end product.
Note: During the reaction, the sulphuric acid acts as the catalyst and is regained back in the end. Also, the nitration process followed is similar for the formation of the nitrobenzene compound, having the electrophilic aromatic substitution reaction.
Complete step by step solution:
It is given that the concentrated nitric acid and sulphuric acid reacts with the nitrobenzene leading to addition of another nitro group by replacement of hydrogen in the benzene ring. This is known as the nitration process. It takes place as follows:
- Firstly the $HN{{O}_{3}}\,and\,{{H}_{2}}S{{O}_{4}}$, react to form the electrophile, as the nitric acid gains proton from sulphuric acid, followed by losing a water molecule and forming the nitronium ion.
- In the nitrobenzene compound, the nitro- group is an electron-withdrawing group which deactivates the ortho- and the para- position for the electrophilic substitution by decreasing the electron density at these position as can be seen in its resonating structures.
This leads to the meta-position being most electron-dense, the favourable position for the electrophile to attach.
- So, when the nitronium ion electrophile attacks the benzene ring of the nitrobenzene compound, to forming the intermediate carbocation, which loses its proton to the Lewis base of $HS{{O}_{4}}^{-}$. Thus, forming a meta-substituted dinitrobenzene compound.
Therefore, the nitration of Nitrobenzene compound forms option (B) 1,3- Dinitrobenzene as the end product.
Note: During the reaction, the sulphuric acid acts as the catalyst and is regained back in the end. Also, the nitration process followed is similar for the formation of the nitrobenzene compound, having the electrophilic aromatic substitution reaction.
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