Answer
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Hint: This reaction is based on the concept of testing the presence of ethers in a chemical substance with the help of a mixture of acetic acid, and HI (hydrogen iodide, or hydroiodic acid). Write down the chemical reaction, and the end product could be known. The reaction between the ether, and HI to produce ethanol is termed as the Zeisel method.
Complete step by step answer:
As we know for unsymmetrical ethers if there is presence of tertiary groups, then the alkyl halide is formed from the smaller alkyl group, but if a tertiary group is present then the halogen gets attached to it.
We have to identify the ether, so let us talk about the given options. The first is 1-methoxybutane, it will form butanol, and methyl iodide when it reacts with HI.
So, we can write the reaction, i.e.
The second is 1-Methoxy-2-methylpropane, it will form methyl iodide, and tertiary alcohol.We can represent the reaction as:
Now, the third is 2-Methoxy-2-methylpropane, it will form methanol, and tertiary halide. We can write the reaction as:
The fourth is methoxybenzene, it will form phenol, and methyl iodide. The chemical reaction is
In the last, we can conclude that the 2-Methoxy-2-methylpropane ether will form methanol on reacting with cold HI.
Hence, the correct option is (C).
Note : As mentioned if a tertiary alkyl group is present, halogen will get attached to it. So in the third option there is formation of tertiary alkyl halide. In the fourth option there is benzene ring, so halogen is attached with methyl group leading to formation of methyl iodide and not methanol.
Complete step by step answer:
As we know for unsymmetrical ethers if there is presence of tertiary groups, then the alkyl halide is formed from the smaller alkyl group, but if a tertiary group is present then the halogen gets attached to it.
We have to identify the ether, so let us talk about the given options. The first is 1-methoxybutane, it will form butanol, and methyl iodide when it reacts with HI.
So, we can write the reaction, i.e.
The second is 1-Methoxy-2-methylpropane, it will form methyl iodide, and tertiary alcohol.We can represent the reaction as:
Now, the third is 2-Methoxy-2-methylpropane, it will form methanol, and tertiary halide. We can write the reaction as:
The fourth is methoxybenzene, it will form phenol, and methyl iodide. The chemical reaction is
In the last, we can conclude that the 2-Methoxy-2-methylpropane ether will form methanol on reacting with cold HI.
Hence, the correct option is (C).
Note : As mentioned if a tertiary alkyl group is present, halogen will get attached to it. So in the third option there is formation of tertiary alkyl halide. In the fourth option there is benzene ring, so halogen is attached with methyl group leading to formation of methyl iodide and not methanol.
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