The acidity of the phenol is due to the _ _ _ _ _ _ of its anion. (This question has multiple correct options.)
(a)- Keto-enol tautomerism
(b)- Electron-withdrawing nature
(c)- Hyperconjugation
(d)- Resonance stabilization
Answer
Verified
430.5k+ views
Hint: Phenol is an organic compound in which a hydroxyl group is present on the benzene ring, when the hydrogen atom of the phenol is removed then there forms a negative charge on the oxygen atom which will start delocalize from its position to the benzene ring.
Complete answer:
Phenol is an organic compound and it is an aromatic compound. It is a compound in which a hydroxyl group, i.e., -OH is present on the benzene ring. So, specifically, we can say phenol is an aromatic alcohol. The formula is ${{C}_{6}}{{H}_{5}}OH$. The structure is given below:
Phenol is acidic in nature but it is a weak acid. The acidic nature can be discussed as, when the hydrogen atom from the hydroxyl group is removed then there is the formation of phenoxide ion, in which the oxygen atom has a negative charge. Now, this negative charge has the ability to delocalize from its position to the benzene ring. So, resonance is possible in the phenoxide ion, due to which it is more stable than the phenol. The resonating structures are given below:
So, due to the resonance stabilization, the phenol is acidic. Also, when the negative charge of the oxygen atom moves towards the ring, there is the formation of the double bond between the oxygen and carbon atom, which is a keto compound. This is due to keto-enol tautomerism.
Therefore, the correct answers are an option (a) and (d).
Note: The double is stronger than the single bond so, the negative charge will easily move from the oxygen atom to the benzene ring. Due to this resonance factor, the aromatic alcohols are more acidic than aliphatic alcohols.
Complete answer:
Phenol is an organic compound and it is an aromatic compound. It is a compound in which a hydroxyl group, i.e., -OH is present on the benzene ring. So, specifically, we can say phenol is an aromatic alcohol. The formula is ${{C}_{6}}{{H}_{5}}OH$. The structure is given below:
Phenol is acidic in nature but it is a weak acid. The acidic nature can be discussed as, when the hydrogen atom from the hydroxyl group is removed then there is the formation of phenoxide ion, in which the oxygen atom has a negative charge. Now, this negative charge has the ability to delocalize from its position to the benzene ring. So, resonance is possible in the phenoxide ion, due to which it is more stable than the phenol. The resonating structures are given below:
So, due to the resonance stabilization, the phenol is acidic. Also, when the negative charge of the oxygen atom moves towards the ring, there is the formation of the double bond between the oxygen and carbon atom, which is a keto compound. This is due to keto-enol tautomerism.
Therefore, the correct answers are an option (a) and (d).
Note: The double is stronger than the single bond so, the negative charge will easily move from the oxygen atom to the benzene ring. Due to this resonance factor, the aromatic alcohols are more acidic than aliphatic alcohols.
Recently Updated Pages
Using the following information to help you answer class 12 chemistry CBSE
Full Form of IASDMIPSIFSIRSPOLICE class 7 social science CBSE
In case of conflict between fundamental rights of citizens class 7 social science CBSE
Can anyone list 10 advantages and disadvantages of friction
What are the Components of Financial System?
Complete the letter given below written to your Principal class null english null
Trending doubts
Which are the Top 10 Largest Countries of the World?
Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE
Draw a labelled sketch of the human eye class 12 physics CBSE
What is the Full Form of PVC, PET, HDPE, LDPE, PP and PS ?
What is a transformer Explain the principle construction class 12 physics CBSE
What are the major means of transport Explain each class 12 social science CBSE