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Hint: The chemical species which have the same type and same quantity of atoms as another species but a different geometric structure are called geometric isomers. These atoms or the groups exhibit different spatial arrangements on both sides of chemical bond or ring structure. The most common type of geometric isomers arise from a ring structure or from a double bond. These types of isomers are called cis and trans isomers.
Complete answer:
To identify the geometrical isomers, check whether there are two different groups on the left-hand side of the bond and two different groups on the right-hand side of the bond. Consider the first compound, it will not show geometrical isomerism because the carbon-carbon double bond is at the end and it will have similar groups on one side. The second compound exhibits geometrical isomerism and can exist in cis and trans forms. The third compound will not exhibit geometrical isomerism because carbon is attached to only one group on one side. The fourth group exhibits geometrical isomerism and exists in cis and trans forms. The second compound and fourth compound show geometric isomerism.
Therefore, option B is the correct answer.
Note:
Geometrical isomerism arises because of the restricted rotation around the carbon-carbon double bond. Because of this hindered rotation around the carbon-carbon double bond, the relative positions of groups or atoms that are attached to the carbon-carbon double bond are fixed. An enone consists of an alkene which is conjugated to a ketone.
Complete answer:
To identify the geometrical isomers, check whether there are two different groups on the left-hand side of the bond and two different groups on the right-hand side of the bond. Consider the first compound, it will not show geometrical isomerism because the carbon-carbon double bond is at the end and it will have similar groups on one side. The second compound exhibits geometrical isomerism and can exist in cis and trans forms. The third compound will not exhibit geometrical isomerism because carbon is attached to only one group on one side. The fourth group exhibits geometrical isomerism and exists in cis and trans forms. The second compound and fourth compound show geometric isomerism.
Therefore, option B is the correct answer.
Note:
Geometrical isomerism arises because of the restricted rotation around the carbon-carbon double bond. Because of this hindered rotation around the carbon-carbon double bond, the relative positions of groups or atoms that are attached to the carbon-carbon double bond are fixed. An enone consists of an alkene which is conjugated to a ketone.
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