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The monovalent ion / radical among the following is:
A.Calcium
B.Nitrate
C. perchloride
D.bicarbonate

Answer
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Hint: In this question, we have to say which among the following are the monovalent ion or radical. Monovalent ion or radicle is a chemical group that has one electron less or more and can form only one covalent bond. Natural water contains monovalent ions such as Na+ , K+ , Cl , Br , HCO3, etc. as well as divalent ions such as Mg2+ , Ca2+ , SO42.

Complete step by step answer:
Now we will discuss the options one by one
The first option is calcium. Calcium forms Ca2+ which is a divalent ion. It has a shortage of two electrons to make it a neutral Ca atom.
The second option is nitrate. Nitrate ion whose chemical formula is NO3 is a monovalent ion with valency 1. It has one extra electron which it can share and form covalent bonds. Nitrate is nitrogen oxoanion formed by the loss of a proton from nitric acid. It is a conjugate base of nitric acid.
The third option is the perchloride. Perchloride ion whose chemical formula is ClO4 is a monovalent anion and a chlorine oxoanion. It is a conjugate base of perchloric acid. It has a valency 1.
The fourth option is bicarbonate. Bicarbonate whose chemical formula is HCO3. A bicarbonate ion is an intermediate form in the deprotonation of carbonic acid. It is a monovalent ion with valency 1.
After the discussion we can conclude that nitrate, perchloride, bicarbonate are the monovalent ions or radicals.
Thus, the correct option is (B), (C), (D).

Note:
Monovalent ions have a valency of 1. A monovalent cation is an ion carrying a positive charge.
 For example:- Na+. A monovalent anion is an ion carrying a negative charge. For example:- Cl
The ions of alkali group metals and halogen groups have monovalent ions.