Answer
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Hint :In a secondary alcohol, the alpha carbon bonded with the alcohol group is bonded with only one hydrogen. Hence, on oxidation, the hydrogen is removed and ketone is formed. Now, there are no other products possible other than ketone. While for a primary alcohol, two hydrogens are bonded to primary carbon, and after oxidation to aldehyde, it still has a chance to carry out further oxidation and thus aldehyde will not be the only preferred product present.
Complete Step By Step Answer:
The oxidation reaction can be defined as the addition of oxygen or the removal of hydrogen from a compound. As hydrogen is unstable in monoatomic state, in oxidation, hydrogen will be removed in pairs and a new bond will be made.
Now, let us consider the reaction of secondary alcohol in presence of oxidising agent, which is shown as
This is the final product obtained after oxidation will be ketone, and no other further oxidation is possible, as there is no hydrogen left on alpha carbon to eliminate.
Now, let us consider the reaction of primary alcohol in presence of excess oxidising agent, which is shown as
Now, here the alpha carbon still contains a hydrogen atom and excess oxidising agent to carry out the oxidation reaction, leading to the formation of carboxylic acid
Hence, due to the excess oxidising agent, the reaction does not stop at aldehyde, and hence not much quantity of aldehyde is obtained.
However, in production of ketone, only ketone is produced and hence the quantity of the product will be higher.
Hence, the correct answer is Option (A).
Note :
We can see from the above reactions that aldehyde is not obtained in the oxidation of primary alcohol, rather it gets further converted to carboxylic acid. Hence, this method is used in the production of carboxylic acid. However, if we are required to produce aldehyde as the final product, we can either take the oxidising agent in limited quantity, so that no catalyst is left to carry the reaction further after the production of aldehyde, or we can take a weak oxidising agent like pyridinium chloro-chromate, which is not capable to replace hydrogen with hydroxyl group, and hence, final product will be aldehyde.
Complete Step By Step Answer:
The oxidation reaction can be defined as the addition of oxygen or the removal of hydrogen from a compound. As hydrogen is unstable in monoatomic state, in oxidation, hydrogen will be removed in pairs and a new bond will be made.
Now, let us consider the reaction of secondary alcohol in presence of oxidising agent, which is shown as
This is the final product obtained after oxidation will be ketone, and no other further oxidation is possible, as there is no hydrogen left on alpha carbon to eliminate.
Now, let us consider the reaction of primary alcohol in presence of excess oxidising agent, which is shown as
Now, here the alpha carbon still contains a hydrogen atom and excess oxidising agent to carry out the oxidation reaction, leading to the formation of carboxylic acid
Hence, due to the excess oxidising agent, the reaction does not stop at aldehyde, and hence not much quantity of aldehyde is obtained.
However, in production of ketone, only ketone is produced and hence the quantity of the product will be higher.
Hence, the correct answer is Option (A).
Note :
We can see from the above reactions that aldehyde is not obtained in the oxidation of primary alcohol, rather it gets further converted to carboxylic acid. Hence, this method is used in the production of carboxylic acid. However, if we are required to produce aldehyde as the final product, we can either take the oxidising agent in limited quantity, so that no catalyst is left to carry the reaction further after the production of aldehyde, or we can take a weak oxidising agent like pyridinium chloro-chromate, which is not capable to replace hydrogen with hydroxyl group, and hence, final product will be aldehyde.