
Which L sugar on oxidation gives an optically active dibasic acid ( 2 - COOH groups)?
A)
B)
C)
D)




Answer
489.9k+ views
2 likes
Hint: In the Fischer projection formula for D-sugar, the bottom most asymmetric carbon atom has hydroxyl group on the right. In the Fischer projection formula for L-sugar, the bottom most asymmetric carbon atom has hydroxyl group on the left. When a sugar molecule is oxidised, the product is a dibasic acid. If a plane of symmetry is present, the product is optically inactive.
Complete step by step answer:
The options B ) and C ) represent D- sugars as in the fischer projection formula, the bottom most asymmetric carbon atom has hydroxyl group on the right. But in the question, you have to find optically active dibasic acid from L-sugar. Hence, the options B ) and C ) are ruled out.
The options A ) and D ) represent L- sugars as in the fischer projection formula, the bottom most asymmetric carbon atom has hydroxyl group on the left.
When a sugar molecule is oxidised, the aldehyde group is converted to a carboxylic group. Similarly, the primary alcohol group is also oxidised to the carboxylic group. Thus, the oxidation of sugar gives a dicarboxylic acid. The product is dibasic acid with two carboxylic acid groups.
When the sugar in option D ) is oxidized, the product dicarboxylic acid contains a plane of symmetry (a mirror plane). Hence, the product is optically inactive. But in the question, you have to find optically active dibasic acid from L-sugar. Hence, the option D ) is ruled out.
When the sugar in option A ) is oxidized, the product dicarboxylic acid does not contain a plane of symmetry (a mirror plane). Hence, the product is optically active. In the question also, you have to find optically active dibasic acid from L-sugar.
Hence, the option A ) is the correct option.
Note: When a symmetry plane is present, the product will be optically inactive due to internal compensation. Such products are meso forms. When a symmetry plane is absent, the product is optically active and present as enantiomeric pairs.
Complete step by step answer:
The options B ) and C ) represent D- sugars as in the fischer projection formula, the bottom most asymmetric carbon atom has hydroxyl group on the right. But in the question, you have to find optically active dibasic acid from L-sugar. Hence, the options B ) and C ) are ruled out.
The options A ) and D ) represent L- sugars as in the fischer projection formula, the bottom most asymmetric carbon atom has hydroxyl group on the left.
When a sugar molecule is oxidised, the aldehyde group is converted to a carboxylic group. Similarly, the primary alcohol group is also oxidised to the carboxylic group. Thus, the oxidation of sugar gives a dicarboxylic acid. The product is dibasic acid with two carboxylic acid groups.
When the sugar in option D ) is oxidized, the product dicarboxylic acid contains a plane of symmetry (a mirror plane). Hence, the product is optically inactive. But in the question, you have to find optically active dibasic acid from L-sugar. Hence, the option D ) is ruled out.
When the sugar in option A ) is oxidized, the product dicarboxylic acid does not contain a plane of symmetry (a mirror plane). Hence, the product is optically active. In the question also, you have to find optically active dibasic acid from L-sugar.




Hence, the option A ) is the correct option.
Note: When a symmetry plane is present, the product will be optically inactive due to internal compensation. Such products are meso forms. When a symmetry plane is absent, the product is optically active and present as enantiomeric pairs.
Latest Vedantu courses for you
Grade 11 Science PCM | CBSE | SCHOOL | English
CBSE (2025-26)
School Full course for CBSE students
₹41,848 per year
Recently Updated Pages
Express the following as a fraction and simplify a class 7 maths CBSE

The length and width of a rectangle are in ratio of class 7 maths CBSE

The ratio of the income to the expenditure of a family class 7 maths CBSE

How do you write 025 million in scientific notatio class 7 maths CBSE

How do you convert 295 meters per second to kilometers class 7 maths CBSE

Write the following in Roman numerals 25819 class 7 maths CBSE

Trending doubts
Give 10 examples of unisexual and bisexual flowers

Draw a labelled sketch of the human eye class 12 physics CBSE

Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE

Differentiate between insitu conservation and exsitu class 12 biology CBSE

What are the major means of transport Explain each class 12 social science CBSE

Franz thinks Will they make them sing in German even class 12 english CBSE
