Answer
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Hint: The isomers of compounds which differ only in the position of the protons and electrons are known as tautomers. When a reaction between such compounds occurs, there is only a transfer of protons.
Complete Step by step answer:
-The phenomenon where a single chemical compound tends to exist in two or more interconvertible structures that are different in terms of the relative position of one atomic nucleus which is generally the hydrogen is known as tautomerism.
-Tautomerism is also known as desmotropism.
- For a compound to exhibit tautomerism, it must have the following structural requirements-
(i) the compound must have at least one alpha hydrogen
(ii) the compound must contain polar molecules and weakly acidic functional groups.
(iii) generally, tautomerism occurs in planar or non-planar molecules.
-Let us now see tautomerism in nitroso compounds.
The shifting of hydrogen produces two forms of tautomers of nitroso compounds, which are ketoxime and aldoxime.
$C{{H}_{3}}-N=O(Ketoxime)\leftrightarrow C{{H}_{2}}=N-OH(Aldoxime)$
-Let us now match with the options and find out which one does exhibit all the structural requirements to be in dynamic equilibrium with their tautomers-
-In option A, the compound has alpha hydrogen, thus it can exhibit tautomerism.
-In option B, the compound has alpha hydrogen, thus it can exhibit tautomerism.
-In option C, the compound does not have alpha hydrogen, hence it will not exhibit tautomerism.
-In option D, the compound does not have alpha hydrogen, hence it will not exhibit tautomerism.
Therefore, the correct answers are options A and B.
Note: Tautomerism happens in the presence of a catalyst which can be either acid-catalyst or base catalyst. In presence of acid-catalyst, the protonation occurs and cation will be delocalized followed by deprotonation occurring in the adjacent position of the cation. In the presence of base-catalyst, the deprotonation occurs in the first step. In this case, anion delocalization occurs instead of cation delocalization and finally, protonation occurs to the different position of the anion.
Complete Step by step answer:
-The phenomenon where a single chemical compound tends to exist in two or more interconvertible structures that are different in terms of the relative position of one atomic nucleus which is generally the hydrogen is known as tautomerism.
-Tautomerism is also known as desmotropism.
- For a compound to exhibit tautomerism, it must have the following structural requirements-
(i) the compound must have at least one alpha hydrogen
(ii) the compound must contain polar molecules and weakly acidic functional groups.
(iii) generally, tautomerism occurs in planar or non-planar molecules.
-Let us now see tautomerism in nitroso compounds.
The shifting of hydrogen produces two forms of tautomers of nitroso compounds, which are ketoxime and aldoxime.
$C{{H}_{3}}-N=O(Ketoxime)\leftrightarrow C{{H}_{2}}=N-OH(Aldoxime)$
-Let us now match with the options and find out which one does exhibit all the structural requirements to be in dynamic equilibrium with their tautomers-
-In option A, the compound has alpha hydrogen, thus it can exhibit tautomerism.
-In option B, the compound has alpha hydrogen, thus it can exhibit tautomerism.
-In option C, the compound does not have alpha hydrogen, hence it will not exhibit tautomerism.
-In option D, the compound does not have alpha hydrogen, hence it will not exhibit tautomerism.
Therefore, the correct answers are options A and B.
Note: Tautomerism happens in the presence of a catalyst which can be either acid-catalyst or base catalyst. In presence of acid-catalyst, the protonation occurs and cation will be delocalized followed by deprotonation occurring in the adjacent position of the cation. In the presence of base-catalyst, the deprotonation occurs in the first step. In this case, anion delocalization occurs instead of cation delocalization and finally, protonation occurs to the different position of the anion.
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