Answer
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Hint: Benzophenone is a colourless crystalline solid with a rose-like smell. It is practically insoluble in water, but readily soluble in organic solvents such as alcohol, acetone, ether, acetic acid, chloroform, and benzene.
Complete step by step solution:
(i) Upon reacting with an excess of benzene in the presence of \[AlC{{l}_{3}}\], benzoyl chloride will give benzophenone by replacing the chlorine with the benzene. It will undergo a reaction called Friedel-Craft’s acylation. It forms an intermediate called benzoylinium cation. The reaction can be given as:
(iii) Similar to the above reaction, when benzoyl chloride reacts with diphenyl cadmium in the presence of dry ether, it replaces the chlorine to form benzophenone. In this reaction, cadmium chloride is formed as a byproduct. The reaction is given as:
So, the correct option is (c).
Additional Information:
Benzophenone is commonly used as a flavor ingredient, a fragrance enhancer, a perfume fixative. It is also used in the manufacturing of agricultural chemicals, insecticides, hypnotic drugs, and other pharmaceuticals.
Benzophenone is used to filter ultraviolet (UV) rays in sunglasses and to prevent UV light from damaging scents and colours in products such as perfumes and soaps.
Benzophenone is also a very good wetting agent for pigments; which can be used in printing to improve the rheological properties and increase the fluidity of inks by acting as a reactive solvent.
Note: An effective sixty six percent yield of benzophenone can be obtained by Friedel-Crafts acylation of benzoyl chloride with an excess of benzene in the presence of anhydrous aluminum chloride.
Complete step by step solution:
(i) Upon reacting with an excess of benzene in the presence of \[AlC{{l}_{3}}\], benzoyl chloride will give benzophenone by replacing the chlorine with the benzene. It will undergo a reaction called Friedel-Craft’s acylation. It forms an intermediate called benzoylinium cation. The reaction can be given as:
(iii) Similar to the above reaction, when benzoyl chloride reacts with diphenyl cadmium in the presence of dry ether, it replaces the chlorine to form benzophenone. In this reaction, cadmium chloride is formed as a byproduct. The reaction is given as:
So, the correct option is (c).
Additional Information:
Benzophenone is commonly used as a flavor ingredient, a fragrance enhancer, a perfume fixative. It is also used in the manufacturing of agricultural chemicals, insecticides, hypnotic drugs, and other pharmaceuticals.
Benzophenone is used to filter ultraviolet (UV) rays in sunglasses and to prevent UV light from damaging scents and colours in products such as perfumes and soaps.
Benzophenone is also a very good wetting agent for pigments; which can be used in printing to improve the rheological properties and increase the fluidity of inks by acting as a reactive solvent.
Note: An effective sixty six percent yield of benzophenone can be obtained by Friedel-Crafts acylation of benzoyl chloride with an excess of benzene in the presence of anhydrous aluminum chloride.
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