Answer
Verified
347.1k+ views
Hint: The carbonyl compounds when heated with excess methanol then two methoxy groups were inserted on the carbonyl carbon.
When alcohols also known as hydroxy compounds undergo dehydration, they form alkenes.
Complete answer: Given compound is \[4 - hydroxy{\text{ }} - 4 - methylpentanal.\]
The parent chain is pentanal, it has five carbon atoms. There is a substitution at fourth carbon.
The numbering should be started from aldehydic carbon.
There are both methyl and hydroxyl groups on \[{4^{th}}\] carbon.
When given compound treats with excess methanol, then the aldehydic carbon converts into the carbon containing methoxy and hydroxyl groups.
As it is treated with excess methanol, the hydroxyl group also converts into methoxy group.
\[{\left( {C{H_3}} \right)_2}C\left( {OH} \right)C{H_2}C{H_2}CH\left( {OH} \right)\left( {C{H_3}} \right) \to {\left( {C{H_3}} \right)_2}C\left( {OH} \right)C{H_2}C{H_2}CH{\left( {OC{H_3}} \right)_2}\]
Now the above product, treated with an acid catalyst, undergoes dehydration.
Dehydration is defined as the loss of water molecules.
The hydroxyl group on \[{4^{th}}\] carbon and hydrogen on \[{3^{rd}}\] carbon ate lost as a water molecule.
Thus, the \[{4^{th}}\] carbon gets positive charge, and the third carbon gets negative charge.
Thereby forms an alkene.
Alkene is an unsaturated organic compound with the presence of a double bond.
Thus, when the given compound undergoes heating with excess methanol in the presence of acid catalyst followed by dehydration it forms a compound namely\[1,1 - dimethoxy - 4 - methyl{\text{ }}3 - pentene\].
Option A will not be formed as the methylation cannot be done on \[{1^{st}}\] carbon.
Option C and D are also not formed as the compound does not undergo cyclisation.
Thus, option B is the correct one.
Note:
The methylation should be done on the aldehydic carbon only. At first one methoxy group attacks on aldehydic carbon, and then due to excess methanol the hydroxyl group can also convert to methoxy group.
The water molecule can be lost from the neighboring carbon atoms only.
When alcohols also known as hydroxy compounds undergo dehydration, they form alkenes.
Complete answer: Given compound is \[4 - hydroxy{\text{ }} - 4 - methylpentanal.\]
The parent chain is pentanal, it has five carbon atoms. There is a substitution at fourth carbon.
The numbering should be started from aldehydic carbon.
There are both methyl and hydroxyl groups on \[{4^{th}}\] carbon.
When given compound treats with excess methanol, then the aldehydic carbon converts into the carbon containing methoxy and hydroxyl groups.
As it is treated with excess methanol, the hydroxyl group also converts into methoxy group.
\[{\left( {C{H_3}} \right)_2}C\left( {OH} \right)C{H_2}C{H_2}CH\left( {OH} \right)\left( {C{H_3}} \right) \to {\left( {C{H_3}} \right)_2}C\left( {OH} \right)C{H_2}C{H_2}CH{\left( {OC{H_3}} \right)_2}\]
Now the above product, treated with an acid catalyst, undergoes dehydration.
Dehydration is defined as the loss of water molecules.
The hydroxyl group on \[{4^{th}}\] carbon and hydrogen on \[{3^{rd}}\] carbon ate lost as a water molecule.
Thus, the \[{4^{th}}\] carbon gets positive charge, and the third carbon gets negative charge.
Thereby forms an alkene.
Alkene is an unsaturated organic compound with the presence of a double bond.
Thus, when the given compound undergoes heating with excess methanol in the presence of acid catalyst followed by dehydration it forms a compound namely\[1,1 - dimethoxy - 4 - methyl{\text{ }}3 - pentene\].
Option A will not be formed as the methylation cannot be done on \[{1^{st}}\] carbon.
Option C and D are also not formed as the compound does not undergo cyclisation.
Thus, option B is the correct one.
Note:
The methylation should be done on the aldehydic carbon only. At first one methoxy group attacks on aldehydic carbon, and then due to excess methanol the hydroxyl group can also convert to methoxy group.
The water molecule can be lost from the neighboring carbon atoms only.
Recently Updated Pages
How many sigma and pi bonds are present in HCequiv class 11 chemistry CBSE
Mark and label the given geoinformation on the outline class 11 social science CBSE
When people say No pun intended what does that mea class 8 english CBSE
Name the states which share their boundary with Indias class 9 social science CBSE
Give an account of the Northern Plains of India class 9 social science CBSE
Change the following sentences into negative and interrogative class 10 english CBSE
Trending doubts
During the region of which ruler Moroccan Traveller class 12 social science CBSE
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE
Difference Between Plant Cell and Animal Cell
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
Give 10 examples for herbs , shrubs , climbers , creepers
Which are the Top 10 Largest Countries of the World?
Write a letter to the principal requesting him to grant class 10 english CBSE
A milkman adds a very small amount of baking soda to class 10 chemistry CBSE