Answer
413.7k+ views
Hint: Both D-glucose and D-fructose are simple monosaccharides. They are carbohydrates. D-glucose is a poly-hydroxy aldehyde and D-fructose is a poly-hydroxy ketone.
Complete step by step answer:
> Select the reagent that can react with either glucose or fructose. The reagent should not react with both. Also during the selected reagent with base, inter-conversion of glucose and fructose should not happen.
> Benedict's test is used to tell if the sugar is reducing or not. When simple carbohydrates have free aldehyde or ketone functional groups, they give positive Benedict’s tests. Thus, Benedict’s test cannot be used to differentiate D-glucose from D-fructose as both glucose and fructose contain free carbonyl groups and will give positive tests. Hence, the option C ) is ruled out.
> Tollens reagent gives positive tests with aldehydes and alpha hydroxy ketones. Glucose being an aldehyde gives positive test with Tollen’s reagent. Fructose being alpha hydroxy ketone gives positive test with Tollen’s reagent. Hence, Tollen’s reagent cannot be used to distinguish glucose and fructose. Hence, the option B) is ruled out.
> Glucose gives a positive test with Fehling's solution. During the reaction with Fehling's solution, the base present converts fructose to glucose. Hence, fructose also gives a positive test with Fehling’s solution. Hence, glucose and fructose cannot be differentiated with Fehling’s solution. Hence, the option A ) is also ruled out.
> D-glucose and D-fructose can be differentiated by test with bromine water.
Bromine water is a mild oxidizing agent and can oxidize aldehydes to carboxylic acids. But bromine water cannot oxidize ketones to carboxylic acids.
Thus, bromine water can oxidise D-glucose to a carboxylic acid. But D-fructose will not be oxidised with bromine water.
Thus, bromine water can be used to distinguish between D-glucose and D-fructose.
Hence, the option D ) is the correct option.
Note: D-glucose and D-fructose, both are simple carbohydrates They have one carbonyl group and five hydroxyl groups in their molecules. Both have same molecular formula of \[{{\text{C}}_6}{{\text{H}}_{12}}{{\text{O}}_6}\]. The only difference is that in glucose, the carbonyl group is the aldehyde group whereas in fructose, the carbonyl group is ketone.
Complete step by step answer:
> Select the reagent that can react with either glucose or fructose. The reagent should not react with both. Also during the selected reagent with base, inter-conversion of glucose and fructose should not happen.
> Benedict's test is used to tell if the sugar is reducing or not. When simple carbohydrates have free aldehyde or ketone functional groups, they give positive Benedict’s tests. Thus, Benedict’s test cannot be used to differentiate D-glucose from D-fructose as both glucose and fructose contain free carbonyl groups and will give positive tests. Hence, the option C ) is ruled out.
> Tollens reagent gives positive tests with aldehydes and alpha hydroxy ketones. Glucose being an aldehyde gives positive test with Tollen’s reagent. Fructose being alpha hydroxy ketone gives positive test with Tollen’s reagent. Hence, Tollen’s reagent cannot be used to distinguish glucose and fructose. Hence, the option B) is ruled out.
> Glucose gives a positive test with Fehling's solution. During the reaction with Fehling's solution, the base present converts fructose to glucose. Hence, fructose also gives a positive test with Fehling’s solution. Hence, glucose and fructose cannot be differentiated with Fehling’s solution. Hence, the option A ) is also ruled out.
> D-glucose and D-fructose can be differentiated by test with bromine water.
Bromine water is a mild oxidizing agent and can oxidize aldehydes to carboxylic acids. But bromine water cannot oxidize ketones to carboxylic acids.
Thus, bromine water can oxidise D-glucose to a carboxylic acid. But D-fructose will not be oxidised with bromine water.
Thus, bromine water can be used to distinguish between D-glucose and D-fructose.
![seo images](https://www.vedantu.com/question-sets/39ca9663-ad20-499a-a2c0-12b1686714eb6188603461090027668.png)
Hence, the option D ) is the correct option.
Note: D-glucose and D-fructose, both are simple carbohydrates They have one carbonyl group and five hydroxyl groups in their molecules. Both have same molecular formula of \[{{\text{C}}_6}{{\text{H}}_{12}}{{\text{O}}_6}\]. The only difference is that in glucose, the carbonyl group is the aldehyde group whereas in fructose, the carbonyl group is ketone.
Recently Updated Pages
How many sigma and pi bonds are present in HCequiv class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Why Are Noble Gases NonReactive class 11 chemistry CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let X and Y be the sets of all positive divisors of class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x and y be 2 real numbers which satisfy the equations class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x 4log 2sqrt 9k 1 + 7 and y dfrac132log 2sqrt5 class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Let x22ax+b20 and x22bx+a20 be two equations Then the class 11 maths CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Trending doubts
Guru Purnima speech in English in 100 words class 7 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Fill the blanks with the suitable prepositions 1 The class 9 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Which are the Top 10 Largest Countries of the World?
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference between Prokaryotic cell and Eukaryotic class 11 biology CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
The Equation xxx + 2 is Satisfied when x is Equal to Class 10 Maths
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Difference Between Plant Cell and Animal Cell
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Change the following sentences into negative and interrogative class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Select the word that is correctly spelled a Twelveth class 10 english CBSE
![arrow-right](/cdn/images/seo-templates/arrow-right.png)
Give 10 examples for herbs , shrubs , climbers , creepers
![arrow-right](/cdn/images/seo-templates/arrow-right.png)