Answer
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Hint: Reaction of hydrogen halide with alcohol gives the alkyl halide and water as products and it is a nucleophilic substitution reaction. The reaction takes place with the formation of the carbocation as an intermediate. Here, halide ion is acting as nucleophile attacks on the electropositive center that is carbocation formed as intermediates in the reaction. Here, the stability of the carbocation formed decides the nature of the product.
Complete step-by-step answer:
Here, in the question alcohol has given is 3-methylbutan-2-ol is secondary alcohol that reacts with hydrogen iodide by SN1 reaction mechanism.
The reaction is completed in three steps which are given as follows:
Step 1: Protonation of alcohol by acid.
Here, we can see that alcohol is pronated to form an intermediate as shown above.
Step 2: Formation of carbocation
Here, the formed intermediate removes water molecules and forms carbocation as an intermediate. Here, secondary carbocation is formed.
Step 3: Formation of product
Here, the secondary carbocation undergoes rearrangement and forms a more stable tertiary carbocation. The tertiary carbocation is then attacked by a nucleophile and the final product 2-iodo-2-methyl butane is formed.
Thus, the action of the hydroiodic acid on 3-methylbutan-2-ol gives 2-iodo-2-methylbutane as a product.
Note:
i) The secondary alcohols in reaction with hydroiodic acid undergo the reaction through the SN2 mechanism.
ii) The reactivity order for alcohols with hydrohalic acid is as follows:
Tertiary> secondary>primary
iii) It indicates tertiary alcohols more radially undergo the reaction compared to secondary and primary.
iv) The stability order of the carbocation is as follows:
Tertiary> secondary> primary
v) The order indicates tertiary carbocation is favored compared to secondary which is favored compared to the primary.
Complete step-by-step answer:
Here, in the question alcohol has given is 3-methylbutan-2-ol is secondary alcohol that reacts with hydrogen iodide by SN1 reaction mechanism.
The reaction is completed in three steps which are given as follows:
Step 1: Protonation of alcohol by acid.
Here, we can see that alcohol is pronated to form an intermediate as shown above.
Step 2: Formation of carbocation
Here, the formed intermediate removes water molecules and forms carbocation as an intermediate. Here, secondary carbocation is formed.
Step 3: Formation of product
Here, the secondary carbocation undergoes rearrangement and forms a more stable tertiary carbocation. The tertiary carbocation is then attacked by a nucleophile and the final product 2-iodo-2-methyl butane is formed.
Thus, the action of the hydroiodic acid on 3-methylbutan-2-ol gives 2-iodo-2-methylbutane as a product.
Note:
i) The secondary alcohols in reaction with hydroiodic acid undergo the reaction through the SN2 mechanism.
ii) The reactivity order for alcohols with hydrohalic acid is as follows:
Tertiary> secondary>primary
iii) It indicates tertiary alcohols more radially undergo the reaction compared to secondary and primary.
iv) The stability order of the carbocation is as follows:
Tertiary> secondary> primary
v) The order indicates tertiary carbocation is favored compared to secondary which is favored compared to the primary.
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