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Hint: The p-nitroacetanilide is an organic compound. Its preparation is carried out through the process of Nitration. It is also called the \[4 - nitroace\tan ilide\]. In this reaction a side product is formed also known as mirror product.
Complete answer:
Let’s see the reaction involved in the preparation of the p-nitroacetanilide
This is an electrophilic substitution reaction. Acetanilide undergoes a Nitration process in presence of Nitric and Sulphuric acid at a temperature of \[288K\]. Mixture of Nitric acid and sulphuric acid is known as Nitrating Mixture. The products formed are p-nitroacetanilide and o-nitroacetanilide. The nitro group will be attached to the para position because \[NHCOC{H_3}\] is an electron releasing group. The product para product is major product (more quantity) and ortho product is minor product (less quantity).
The minor product that is o-nitroacetanilide is separated from the p-nitroacetanilide by dissolving the solution of both products in Ethanol. o-nitroacetanilide is more soluble in alcohol as compared to the p-nitroacetanilide. During Crystallization process the o-nitroacetanilide remains in the solution as it is soluble in alcohol and p-nitroacetanilide crystallises. Then crystals of the p-nitroacetanilide are easily filtered with the help of a filter paper from the solution. The crystals of the p-nitroacetanilide are colourless.
Note:
Nitro anilines can be prepared from the product formed in this reaction as direct nitration of aniline is not possible because amino groups are oxidised when treated with nitrating mixture. For preparing nitroaniline acetanilide is subjected to nitration to form p-nitroacetanilide. Then p-acetanilide is subjected to hydrolysis to obtain p-nitroaniline.
Complete answer:
Let’s see the reaction involved in the preparation of the p-nitroacetanilide
This is an electrophilic substitution reaction. Acetanilide undergoes a Nitration process in presence of Nitric and Sulphuric acid at a temperature of \[288K\]. Mixture of Nitric acid and sulphuric acid is known as Nitrating Mixture. The products formed are p-nitroacetanilide and o-nitroacetanilide. The nitro group will be attached to the para position because \[NHCOC{H_3}\] is an electron releasing group. The product para product is major product (more quantity) and ortho product is minor product (less quantity).
The minor product that is o-nitroacetanilide is separated from the p-nitroacetanilide by dissolving the solution of both products in Ethanol. o-nitroacetanilide is more soluble in alcohol as compared to the p-nitroacetanilide. During Crystallization process the o-nitroacetanilide remains in the solution as it is soluble in alcohol and p-nitroacetanilide crystallises. Then crystals of the p-nitroacetanilide are easily filtered with the help of a filter paper from the solution. The crystals of the p-nitroacetanilide are colourless.
Note:
Nitro anilines can be prepared from the product formed in this reaction as direct nitration of aniline is not possible because amino groups are oxidised when treated with nitrating mixture. For preparing nitroaniline acetanilide is subjected to nitration to form p-nitroacetanilide. Then p-acetanilide is subjected to hydrolysis to obtain p-nitroaniline.
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